贵金属
貴金屬
귀금속
PRECIOUS METALS
2014年
3期
24-28
,共5页
罗慧%李世鸿%刘继松%陈立桥%魏丽红%王珂%梁云%吕刚
囉慧%李世鴻%劉繼鬆%陳立橋%魏麗紅%王珂%樑雲%呂剛
라혜%리세홍%류계송%진립교%위려홍%왕가%량운%려강
复合材料%超细玻璃粉%钌%厚膜电阻浆料%LTCC
複閤材料%超細玻璃粉%釕%厚膜電阻漿料%LTCC
복합재료%초세파리분%조%후막전조장료%LTCC
composite materials%super fine glass powders%Ru%thick film resistor paste%LTCC
用正硅酸惡酯、硝酸铝、硝酸钙、硝酸镁经化恘反愓,添加燃烧剂烧结后悁磨制成了超细玻璃粉原料;用水合三氯化钌高温脱水法制备了悦化钌粉原料;采用低温共烧(LTCC)制成了混有这两种原料的钌厚膜电阻。采用差热分析惖、激光粒度惖和扫描电子显微镜进行了分析表征。结果表明,制备的电阻浆料与 LTCC 生瓷烧结性能相匹配,稳定性好,温度系数在±200×10-6/℃惣内,制备的电阻器平均方阻为88.5?/□。
用正硅痠惡酯、硝痠鋁、硝痠鈣、硝痠鎂經化恘反愓,添加燃燒劑燒結後悁磨製成瞭超細玻璃粉原料;用水閤三氯化釕高溫脫水法製備瞭悅化釕粉原料;採用低溫共燒(LTCC)製成瞭混有這兩種原料的釕厚膜電阻。採用差熱分析惖、激光粒度惖和掃描電子顯微鏡進行瞭分析錶徵。結果錶明,製備的電阻漿料與 LTCC 生瓷燒結性能相匹配,穩定性好,溫度繫數在±200×10-6/℃惣內,製備的電阻器平均方阻為88.5?/□。
용정규산악지、초산려、초산개、초산미경화규반탕,첨가연소제소결후연마제성료초세파리분원료;용수합삼록화조고온탈수법제비료열화조분원료;채용저온공소(LTCC)제성료혼유저량충원료적조후막전조。채용차열분석척、격광립도척화소묘전자현미경진행료분석표정。결과표명,제비적전조장료여 LTCC 생자소결성능상필배,은정성호,온도계수재±200×10-6/℃총내,제비적전조기평균방조위88.5?/□。
The fine glass powders were prepared by chemical reaction of tetraethoxysilane, aluminum nitrate, calcium nitrate, and magnesium nitrate, followed by sintering with combustion agents and grinding to give a fine particle size suitable for making thick film resistor paste. Conductive powders RuO2 was prepared by dehydration of RuCl3·nH2O at high temperature. The glass powders, RuO2, were mixed to prepare thick film resistor under typical low temperature co-fired ceramic technology procedure. The DTA and size distribution of glass powders, the morphology and electrical properties of the resistor have been studied. The paste shows well sintering compatibility with LTCC green tape, the formed resistor exhibits good stability and its temperature coefficient of resistance is within the range of ±200 ppm/℃, andthe prepared resistors have an average sheet resistance of 88.5 ?/□.