CAJ | 학술논문

合成了一种新的含异马来二氰基二硫烯(i-mnt)镍(II)配阴离子的2-萘亚甲基哌啶([2-NaMePid]+)盐(简记为[2-NaMePid]2[Ni(i-mnt)2])。基于元素分析、摩尔电导测定,以及红外光谱、紫外-可见光谱、X 射线单晶衍射分析确定了其组成和结构。结果显示,合成的哌啶盐属于三斜晶系,P-1空间群,分子中的[Ni (i-mnt)2]2-阴离子通过短程的 C…N 作用形成一维链；阴、阳离子之间的静电作用,以及 N- H…N 和 C- H…Ni氢键促进分子的堆积和稳定。
합성료일충신적함이마래이청기이류희(i-mnt)얼(II)배음리자적2-내아갑기고정([2-NaMePid]+)염(간기위[2-NaMePid]2[Ni(i-mnt)2])。기우원소분석、마이전도측정,이급홍외광보、자외-가견광보、X 사선단정연사분석학정료기조성화결구。결과현시,합성적고정염속우삼사정계,P-1공간군,분자중적[Ni (i-mnt)2]2-음리자통과단정적 C…N 작용형성일유련；음、양리자지간적정전작용,이급 N- H…N 화 C- H…Ni경건촉진분자적퇴적화은정。
A new salt,[2-NaBzPid]2 [Ni(i-mnt)2 ]([2-NaMePid]+ =2-naphthylmethylene pip-eridinium,i-mnt2 - =iso-maleonitriledithiolate)was synthesized.The composition and struc-ture of as-synthesized product were determined by elemental analysis and molar conductivity measurement as well as infrared spectrometry,ultraviolet-visible light absorption spectrometry and single crystal X-ray diffraction.Results show that as-synthesized [2-NaBzPid]2 [Ni (i-mnt)2 ]salt crystallizes in the triclinic space group P-1,and its anions form a one-dimensional chain through short C…N interactions.The electrostatic interaction together with the N-H…N and C-H…Ni hydrogen bonds contributes to enhancing the stacking and increasing the sta-bility of the target product molecule.