CAJ | 학술논문

利用水热合成法，以金属盐NiSO4·6H2O与三脚架配体1，3，5-三（1-咪唑基）苯（tib）进行组装，得到了一个结构新颖的有序金属-有机框架（MOFs）{[Ni3（tib）2（H2O）12]（SO4）3}n（1）.利用X-射线单晶衍射仪检测其晶体结构，并进行元素分析，红外光谱射线，粉末衍射等相关表征.配合物1为一个典型的（6，3）拓扑二维蜂窝网结构，由于π-π空间叠加效应和氢键相互作用形成了稳定的三维结构.对配合物1介电性能进行测定，发现其在138℃时达到最大的介电异常值10.08，为典型的介电材料，通过热重分析，表明此材料具有较好的热力学稳定性，对新型多维MOFs及新型介电性能材料的开发具有借鉴和指导意义.
이용수열합성법，이금속염NiSO4·6H2O여삼각가배체1，3，5-삼（1-미서기）분（tib）진행조장，득도료일개결구신영적유서금속-유궤광가（MOFs）{[Ni3（tib）2（H2O）12]（SO4）3}n（1）.이용X-사선단정연사의검측기정체결구，병진행원소분석，홍외광보사선，분말연사등상관표정.배합물1위일개전형적（6，3）탁복이유봉와망결구，유우π-π공간첩가효응화경건상호작용형성료은정적삼유결구.대배합물1개전성능진행측정，발현기재138℃시체도최대적개전이상치10.08，위전형적개전재료，통과열중분석，표명차재료구유교호적열역학은정성，대신형다유MOFs급신형개전성능재료적개발구유차감화지도의의.
The new novel metal-organic framework (MOFs){[Ni3(tib)2(H2O)12](SO4)3}n(1) is obtained by hydrothermal reaction of the metal salt NiSO4·6H2O and the three-connecting ligand 1,3,5-tris(1-imidazolyl) benzene (tib). The crystal data and structure are established by single-crystal X-ray diffraction analysis, and characterized by elemental, IR, XRD, et al. and by using SHELXL-97 software for the structure elucidation and Topos40 software for its topology analysis. It shows that complex 1 is a 2D network honeycomb networks with (6,3) topology, which is further linked to three-dimensional (3D) frameworks by the spatial additive effect of π-π and interaction of hydrogen bonds. Dielectric constant studies show that the εmax of complex 1 reaches a value of about 10.08 at 138 ℃, which is the typical dielectric material. This material has good thermal stability indicated by thermogravimetric, which provides a reference and guidance for the development of the novel multidimensional MOFS and dielectric properties of new materials.