有色金属科学与工程
有色金屬科學與工程
유색금속과학여공정
JIANGXI NONFERROUS METALS
2014年
4期
55-58
,共4页
α-Fe2O3%纳米线%气敏特性%乙醇
α-Fe2O3%納米線%氣敏特性%乙醇
α-Fe2O3%납미선%기민특성%을순
α-Fe2O3%nanowires%gas sensing%ethanol
家用燃气事故、汽车尾气和工业废气等问题日趋严重,传统气敏材料已很难满足对气体监测越来越高的要求,纳米结构α-Fe2O3因其热稳定性好、选择性好,以及无毒、抗腐蚀性强、环境友好、价格低廉等已成为最重要的气敏材料之一.采用简单的热氧化法成功制备了α-Fe2O3纳米线.纳米线平均直径为20~50 nm,长度可达1~5μm;以制备的α-Fe2O3纳米线为探测材料的气敏元件在50×10-6乙醇气氛中的最佳工作温度为383°C,灵敏度可达2.4,响应和恢复时间分别为13 s和6 s.基于α-Fe2O3纳米线制备的气敏元件在乙醇中的气敏机理为表面电阻控制型.
傢用燃氣事故、汽車尾氣和工業廢氣等問題日趨嚴重,傳統氣敏材料已很難滿足對氣體鑑測越來越高的要求,納米結構α-Fe2O3因其熱穩定性好、選擇性好,以及無毒、抗腐蝕性彊、環境友好、價格低廉等已成為最重要的氣敏材料之一.採用簡單的熱氧化法成功製備瞭α-Fe2O3納米線.納米線平均直徑為20~50 nm,長度可達1~5μm;以製備的α-Fe2O3納米線為探測材料的氣敏元件在50×10-6乙醇氣氛中的最佳工作溫度為383°C,靈敏度可達2.4,響應和恢複時間分彆為13 s和6 s.基于α-Fe2O3納米線製備的氣敏元件在乙醇中的氣敏機理為錶麵電阻控製型.
가용연기사고、기차미기화공업폐기등문제일추엄중,전통기민재료이흔난만족대기체감측월래월고적요구,납미결구α-Fe2O3인기열은정성호、선택성호,이급무독、항부식성강、배경우호、개격저렴등이성위최중요적기민재료지일.채용간단적열양화법성공제비료α-Fe2O3납미선.납미선평균직경위20~50 nm,장도가체1~5μm;이제비적α-Fe2O3납미선위탐측재료적기민원건재50×10-6을순기분중적최가공작온도위383°C,령민도가체2.4,향응화회복시간분별위13 s화6 s.기우α-Fe2O3납미선제비적기민원건재을순중적기민궤리위표면전조공제형.
The traditional gas-sensitive materials has been difficult to meet the increasing demands in gas monitoring because of the more and more serious problems in domestic gas , vehicle exhaust and industrial emissions. α-Fe2O3 nanostructures become one of the most important gas-sensitive materials due to its good thermal stability, high selectivity, non-toxic, anti-corrosive, environmental friendliness and low price. Herein, single monoclinic crystalline α-Fe2O3 nanowires are synthesized by simple thermal oxidation. α-Fe2O3 nanowires have an average 20~50 nm in diameters, and a length up to 1~5 μm. The optimum working temperature is about 383 ° C and sensitivity is up to 2.4 in 50 ppm ethanol atmosphere. The corresponding recovery and response time were 13 s and 6 s, respectively. Gas sensing mechanism in ethanol for the sensor based onα-Fe2O3 nanowires are surface resistivity controlled type.