CAJ | 학술논문

以水性聚氨酯作为种子乳液，与含全氟己基乙基丙烯酸酯（ C6 F）、丙烯酸羟丙酯（ HPAA）、甲基丙烯酸十八酯（ SMA）、苯乙烯（ ST）等进行乳液聚合，制得了含氟聚丙烯酸酯-聚氨酯复合乳液（ WPUAF）。通过红外光谱、纳米粒度仪、场发射扫描电镜（ FE-SEM）等对WPUAF的结构、粒径、成膜形貌以及应用性能进行研究。结果表明， WPUAF 能在纤维表面形成一层致密的疏水膜；在WPUAF的用量为3 g/100 g H2 O，并在100℃烘焙5 min、180℃定型2 min的工艺条件下，整理后的织物与水的接触角达到136?9°，疏油等级为6级。
이수성취안지작위충자유액，여함전불기기을기병희산지（ C6 F）、병희산간병지（ HPAA）、갑기병희산십팔지（ SMA）、분을희（ ST）등진행유액취합，제득료함불취병희산지-취안지복합유액（ WPUAF）。통과홍외광보、납미립도의、장발사소묘전경（ FE-SEM）등대WPUAF적결구、립경、성막형모이급응용성능진행연구。결과표명， WPUAF 능재섬유표면형성일층치밀적소수막；재WPUAF적용량위3 g/100 g H2 O，병재100℃홍배5 min、180℃정형2 min적공예조건하，정리후적직물여수적접촉각체도136?9°，소유등급위6급。
The fluorinated polyacrylate-polyurethane emulsion ( WPUAF) was prepared by emulsion polymeriza-tion with 2-( perfluorohexy ) ethyl acrylate ( C6 F )、octadecyl methacrylate ( SMA ) , 2-hydroxypropyl acrylate ( HPAA) , styrene( ST) and the seeding emulsion of waterborne polyurethane. The structure, film morphology and application performance of WPUAF were studied by infrared spectroscopy, nanoparticle size analyzerand field spec-trum scanning electron microscopy ( FE-SEM) , etc. The result showed that WPUAF formed dense membrane which was hydrophobic on the surface of fiber. The dried fabric samples was submerged into 3%solution of WPUAF in H2 O,then dried at 100 ℃ during 5 min and finalized the design at 180 ℃ for 2 min. The water contact angle of fabric was 136?9 ° with the oil-repellent grade 6 .