中国材料进展
中國材料進展
중국재료진전
MATERIALS CHINA
2014年
7期
418-425
,共8页
叶章基%王晶晶%蔺存国%陈光章%李瑛%吴建华
葉章基%王晶晶%藺存國%陳光章%李瑛%吳建華
협장기%왕정정%린존국%진광장%리영%오건화
海洋%防腐%防污%涂料
海洋%防腐%防汙%塗料
해양%방부%방오%도료
marine%anticorrosive%antifouling%coating
简要论述了海洋防腐蚀防污涂料的发展历史和研究现状,重点论述了舰船高性能防腐蚀防污涂料的最新研究进展。有机锡自抛光防污涂料被禁止使用之后,基于丙烯酸锌、丙烯酸铜和丙烯酸硅烷酯的自抛光防污涂料得到了广泛应用。基于含防污功能基团树脂的防污涂料、基于降解树脂的防污涂料以及基于表面结构特性的防污涂料技术成为当前防污涂料研究的热点。文中详细报道了降解树脂的结构对降解性能及力学性能影响规律,以及表面结构特性对污损释放型防污涂料防污性能的影响规律。随着环境保护法规的日趋严格,防腐蚀涂料向无溶剂(或高固体)、长效方向发展。报道了提高涂层的湿态附着力和致密性的方法,采用该方法可以大幅提高涂层的力学性能和耐蚀性能,满足了远洋和深海装备发展需求。
簡要論述瞭海洋防腐蝕防汙塗料的髮展歷史和研究現狀,重點論述瞭艦船高性能防腐蝕防汙塗料的最新研究進展。有機錫自拋光防汙塗料被禁止使用之後,基于丙烯痠鋅、丙烯痠銅和丙烯痠硅烷酯的自拋光防汙塗料得到瞭廣汎應用。基于含防汙功能基糰樹脂的防汙塗料、基于降解樹脂的防汙塗料以及基于錶麵結構特性的防汙塗料技術成為噹前防汙塗料研究的熱點。文中詳細報道瞭降解樹脂的結構對降解性能及力學性能影響規律,以及錶麵結構特性對汙損釋放型防汙塗料防汙性能的影響規律。隨著環境保護法規的日趨嚴格,防腐蝕塗料嚮無溶劑(或高固體)、長效方嚮髮展。報道瞭提高塗層的濕態附著力和緻密性的方法,採用該方法可以大幅提高塗層的力學性能和耐蝕性能,滿足瞭遠洋和深海裝備髮展需求。
간요논술료해양방부식방오도료적발전역사화연구현상,중점논술료함선고성능방부식방오도료적최신연구진전。유궤석자포광방오도료피금지사용지후,기우병희산자、병희산동화병희산규완지적자포광방오도료득도료엄범응용。기우함방오공능기단수지적방오도료、기우강해수지적방오도료이급기우표면결구특성적방오도료기술성위당전방오도료연구적열점。문중상세보도료강해수지적결구대강해성능급역학성능영향규률,이급표면결구특성대오손석방형방오도료방오성능적영향규률。수착배경보호법규적일추엄격,방부식도료향무용제(혹고고체)、장효방향발전。보도료제고도층적습태부착력화치밀성적방법,채용해방법가이대폭제고도층적역학성능화내식성능,만족료원양화심해장비발전수구。
The development history and research status of marine anticorrosive and antifouling coating were introduced briefly.The latest research progresses of high performance anticorrosive and antifouling warship coatings were discussed emphatically.Self-polishing antifouling coatings based on acrylic acid zinc,acrylic acid copper and acrylic acid silane have been used widely after organictin self-polishing being prohibited.The technologies based on biocide grafting,degrad-able resin and surface micro-structure are the topic research in antifouling coating.The relationships between structure and degradation properties,mechanical properties of the degradable resin were discussed in detail.The relationships between surface mico-structure and antifouling properties of the fouling release coating were also discussed.The development direc-tions of anticorrosive coating are solventless (or high solid content)and long-term service with more and more strict envi-ronmental protection laws.This paper reported a method for improving wet adhesion and compactness,which can greatly improve mechanical properties and corrosion resistance of anticorrosive coatings.These anticorrosive and antifouling coat-ings meet the development needs of the ocean liner and deep-sea equipments.