中国有色金属学报
中國有色金屬學報
중국유색금속학보
THE CHINESE JOURNAL OF NONFERROUS METALS
2014年
8期
2164-2170
,共7页
杨喜云%刘政坤%郭孔彬%徐徽%石西昌
楊喜雲%劉政坤%郭孔彬%徐徽%石西昌
양희운%류정곤%곽공빈%서휘%석서창
难处理金矿%硫脲%硫氰酸钠%浸出剂
難處理金礦%硫脲%硫氰痠鈉%浸齣劑
난처리금광%류뇨%류청산납%침출제
refractory gold ore%thiourea%thiocyanate%lixiviant
采用高温焙烧、硫脲-硫氰酸钠浸出难处理金矿中的金,研究焙烧温度、硫氰酸钠浓度、硫脲(Tu)浓度、Fe3+浓度、pH值、浸出温度和时间对金浸出率的影响,得到混合体系浸金的最优条件,并研究浸出过程中硫氰酸钠和硫脲的稳定性。结果表明:金的浸出率达到93.1%,超过相同条件下单一体系中的浸出率之和,硫脲与硫氰酸钠摩尔比对金浸出率和金电极稳定电位影响较大;硫氰酸钠使硫脲的稳定性降低,而硫脲使硫氰酸钠的稳定性增强。
採用高溫焙燒、硫脲-硫氰痠鈉浸齣難處理金礦中的金,研究焙燒溫度、硫氰痠鈉濃度、硫脲(Tu)濃度、Fe3+濃度、pH值、浸齣溫度和時間對金浸齣率的影響,得到混閤體繫浸金的最優條件,併研究浸齣過程中硫氰痠鈉和硫脲的穩定性。結果錶明:金的浸齣率達到93.1%,超過相同條件下單一體繫中的浸齣率之和,硫脲與硫氰痠鈉摩爾比對金浸齣率和金電極穩定電位影響較大;硫氰痠鈉使硫脲的穩定性降低,而硫脲使硫氰痠鈉的穩定性增彊。
채용고온배소、류뇨-류청산납침출난처리금광중적금,연구배소온도、류청산납농도、류뇨(Tu)농도、Fe3+농도、pH치、침출온도화시간대금침출솔적영향,득도혼합체계침금적최우조건,병연구침출과정중류청산납화류뇨적은정성。결과표명:금적침출솔체도93.1%,초과상동조건하단일체계중적침출솔지화,류뇨여류청산납마이비대금침출솔화금전겁은정전위영향교대;류청산납사류뇨적은정성강저,이류뇨사류청산납적은정성증강。
Gold was extracted from refractory gold ore using a process of roasting followed by thiourea-thiocyanate leaching. The effects of roasting temperature, initial concentrations of thiocyanate, thiourea and ferric as well as pH value, leaching temperature and time on the leaching rate of gold were investigated. The results show that the gold leaching rate is 93.1%under the optimum conditions, and the leaching rate in mixed system is greater than the sum of leaching rate in solutions with each individual lixiviant. The mole ratio of thiourea to thiocyanate has significant influence on the leaching rate of gold and open potential. Thiocyanate accelerates the decomposition of thiourea whereas thiourea alleviates the decomposition of thiocyante.