化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
9期
2495-2500,2516
,共7页
杨红强%丁明山%胡斌%任嗣利
楊紅彊%丁明山%鬍斌%任嗣利
양홍강%정명산%호빈%임사리
油砂%溶剂萃取%回收率%溶解性%传质
油砂%溶劑萃取%迴收率%溶解性%傳質
유사%용제췌취%회수솔%용해성%전질
oil sands%solvent extraction%recovery%solubility%mass transfer
开发了一种水辅助溶剂法从油砂中提取沥青的技术。该方法通过在油砂固相与有机溶剂间介入水层提取油砂中的沥青。以内蒙古扎赉特旗油砂矿为研究对象,考察了温度、剂砂质量比、提取时间、甲苯在复合溶剂中的含量及溶剂的种类与性质对沥青回收率高低的影响,结果表明:最佳提取条件为提取温度50℃,剂砂质量比1∶1,提取时间25min。沥青回收率与提取溶剂的性质紧密相关,水层介入有效降低了固体微粒组分在有机相中的含量,且便于后续的有机相与泥砂相的分离。通过对各种溶剂提取的沥青进行组分分析,发现各种溶剂对沥青提取能力的差异性源于溶剂的化学组成和结构不同。本文相关研究结果对溶剂法提取油砂中沥青技术及溶剂种类的选择具有指导作用。
開髮瞭一種水輔助溶劑法從油砂中提取瀝青的技術。該方法通過在油砂固相與有機溶劑間介入水層提取油砂中的瀝青。以內矇古扎賚特旂油砂礦為研究對象,攷察瞭溫度、劑砂質量比、提取時間、甲苯在複閤溶劑中的含量及溶劑的種類與性質對瀝青迴收率高低的影響,結果錶明:最佳提取條件為提取溫度50℃,劑砂質量比1∶1,提取時間25min。瀝青迴收率與提取溶劑的性質緊密相關,水層介入有效降低瞭固體微粒組分在有機相中的含量,且便于後續的有機相與泥砂相的分離。通過對各種溶劑提取的瀝青進行組分分析,髮現各種溶劑對瀝青提取能力的差異性源于溶劑的化學組成和結構不同。本文相關研究結果對溶劑法提取油砂中瀝青技術及溶劑種類的選擇具有指導作用。
개발료일충수보조용제법종유사중제취력청적기술。해방법통과재유사고상여유궤용제간개입수층제취유사중적력청。이내몽고찰뢰특기유사광위연구대상,고찰료온도、제사질량비、제취시간、갑분재복합용제중적함량급용제적충류여성질대력청회수솔고저적영향,결과표명:최가제취조건위제취온도50℃,제사질량비1∶1,제취시간25min。력청회수솔여제취용제적성질긴밀상관,수층개입유효강저료고체미립조분재유궤상중적함량,차편우후속적유궤상여니사상적분리。통과대각충용제제취적력청진행조분분석,발현각충용제대력청제취능력적차이성원우용제적화학조성화결구불동。본문상관연구결과대용제법제취유사중력청기술급용제충류적선택구유지도작용。
Water-assisted solvent extraction processes (WASEPs) were developed by introducing a water layer between the oil sands and solvent to extract bitumen. The function of the introduced water layer in the WASEPs is to effectively reduce the fine solids content in the solvent phase and make it easy to separate bitumen solution from solids. Effects of the solvent type on bitumen recovery were investigated and the extraction conditions were optimized. The results showed that bitumen recovery was closely related to the solvent compositions and chemical structure. The optimal extraction condition was stirring at 50℃ for 25 minutes using a ratio of oil sands to solvent at 1∶1(wt/wt). The reason of different extraction abilities for various solvents was revealed by analyzing the component of extracted bitumen. It may be useful to guide the solvent extraction processes and solvent selection.