化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
9期
2350-2355,2379
,共7页
戈明亮%郑罗云%周向阳%贾志欣
戈明亮%鄭囉雲%週嚮暘%賈誌訢
과명량%정라운%주향양%가지흔
甘蔗渣%接枝%影响因素%吸附
甘蔗渣%接枝%影響因素%吸附
감자사%접지%영향인소%흡부
bagasse%graft copolymerization%impact factors%adsorption
甘蔗渣(SCB)作为一种重要的植物纤维,是可再生资源,其接枝技术日益受到重视。本文先介绍了SCB的结构、物理化学性质以及接枝机理,再重点评述了预处理方式、不同的接枝单体和溶剂、引发方式对SCB接枝的影响。预处理破坏了SCB的超分子结构从而提高SCB的反应可及性;一般溶剂不能破坏SCB的多相结构,反应在SCB表面进行,纤维素溶剂和一些二元体系溶剂可溶解SCB而实现分子水平上的接枝;引发剂浓度对接枝率的提高有一个最佳范围;接枝单体用量直接影响接枝率。最后指出SCB接枝物在离子交换、重金属离子吸附、吸油和吸水保水等方面的应用前景,并建议SCB接枝技术应向着接枝效率高、接枝物性能稳定、工艺绿色环保和开发成本低等方向发展。
甘蔗渣(SCB)作為一種重要的植物纖維,是可再生資源,其接枝技術日益受到重視。本文先介紹瞭SCB的結構、物理化學性質以及接枝機理,再重點評述瞭預處理方式、不同的接枝單體和溶劑、引髮方式對SCB接枝的影響。預處理破壞瞭SCB的超分子結構從而提高SCB的反應可及性;一般溶劑不能破壞SCB的多相結構,反應在SCB錶麵進行,纖維素溶劑和一些二元體繫溶劑可溶解SCB而實現分子水平上的接枝;引髮劑濃度對接枝率的提高有一箇最佳範圍;接枝單體用量直接影響接枝率。最後指齣SCB接枝物在離子交換、重金屬離子吸附、吸油和吸水保水等方麵的應用前景,併建議SCB接枝技術應嚮著接枝效率高、接枝物性能穩定、工藝綠色環保和開髮成本低等方嚮髮展。
감자사(SCB)작위일충중요적식물섬유,시가재생자원,기접지기술일익수도중시。본문선개소료SCB적결구、물이화학성질이급접지궤리,재중점평술료예처리방식、불동적접지단체화용제、인발방식대SCB접지적영향。예처리파배료SCB적초분자결구종이제고SCB적반응가급성;일반용제불능파배SCB적다상결구,반응재SCB표면진행,섬유소용제화일사이원체계용제가용해SCB이실현분자수평상적접지;인발제농도대접지솔적제고유일개최가범위;접지단체용량직접영향접지솔。최후지출SCB접지물재리자교환、중금속리자흡부、흡유화흡수보수등방면적응용전경,병건의SCB접지기술응향착접지효솔고、접지물성능은정、공예록색배보화개발성본저등방향발전。
Sugar cane bagasse(SCB)grafting technology has attracted increasing attention by researchers,because SCB is an important kind of plant fiber and belongs to renewable resources. The SCB’s structure,physical and chemical properties as well as grafting mechanism are described,and the influence of pretreatment,monomer,solvent,initiation mode on SCB grafting is analyzed. Pretreatment destroys SCB’s supramolecular structures,improving the reactivity of SCB. General solvent cannot destroy SCB’s multiphase structure,therefore grafting only occur on the surface of SCB,but cellulose solvents and some binary solvents can dissolve SCB and make grafting occur at molecular level. Initiator concentration has an optimal range for the increase of grafting rate. The amount of grafting monomer affects grafting rate directly. SCB grafting polymer can be used as ion exchanger,heavy metal ion adsorbent,oil-absorptive materials,water absorbing &holding materials. Future research directions are proposed. SCB grafting polymerization should have higher percentage of grafting and be more stable,and grafting technology should be environmentally friendly and low-cost.