化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
9期
2229-2234
,共6页
褚良银%汪伟%巨晓洁%谢锐
褚良銀%汪偉%巨曉潔%謝銳
저량은%왕위%거효길%사예
微流体学%微反应器%流动%界面%加工制造%功能材料
微流體學%微反應器%流動%界麵%加工製造%功能材料
미류체학%미반응기%류동%계면%가공제조%공능재료
microfluidics%microreactor%flow%interface%fabrication%functional materials
微流控技术由于具有优异的流体微尺度相界面调控能力,是实现微结构精确可控的新型功能材料的设计制备与性能调控的重要新兴手段。本文介绍了微流控技术可控构建稳定相界面结构的两大体系:一是具有封闭液-液相界面的乳液液滴体系;二是具有非封闭层状和环状液-液相界面的层流体系。回顾了利用微流控技术构建的这两类稳定相界面结构体系制备三大类功能材料的研究进展:一是利用乳液液滴体系制备微球微囊材料;二是利用层状层流体系制备微通道膜材料;三是利用环状层流体系制备超细纤维材料。指出微流控技术为实现功能材料的小尺度化、薄膜化、纤维化、多功能化、材料元件一体化等带来了新的机遇,提出应进一步深入系统地认识液-液相界面设计与调控以及功能材料合成过程的基本规律和机理。
微流控技術由于具有優異的流體微呎度相界麵調控能力,是實現微結構精確可控的新型功能材料的設計製備與性能調控的重要新興手段。本文介紹瞭微流控技術可控構建穩定相界麵結構的兩大體繫:一是具有封閉液-液相界麵的乳液液滴體繫;二是具有非封閉層狀和環狀液-液相界麵的層流體繫。迴顧瞭利用微流控技術構建的這兩類穩定相界麵結構體繫製備三大類功能材料的研究進展:一是利用乳液液滴體繫製備微毬微囊材料;二是利用層狀層流體繫製備微通道膜材料;三是利用環狀層流體繫製備超細纖維材料。指齣微流控技術為實現功能材料的小呎度化、薄膜化、纖維化、多功能化、材料元件一體化等帶來瞭新的機遇,提齣應進一步深入繫統地認識液-液相界麵設計與調控以及功能材料閤成過程的基本規律和機理。
미류공기술유우구유우이적류체미척도상계면조공능력,시실현미결구정학가공적신형공능재료적설계제비여성능조공적중요신흥수단。본문개소료미류공기술가공구건은정상계면결구적량대체계:일시구유봉폐액-액상계면적유액액적체계;이시구유비봉폐층상화배상액-액상계면적층류체계。회고료이용미류공기술구건적저량류은정상계면결구체계제비삼대류공능재료적연구진전:일시이용유액액적체계제비미구미낭재료;이시이용층상층류체계제비미통도막재료;삼시이용배상층류체계제비초세섬유재료。지출미류공기술위실현공능재료적소척도화、박막화、섬유화、다공능화、재료원건일체화등대래료신적궤우,제출응진일보심입계통지인식액-액상계면설계여조공이급공능재료합성과정적기본규률화궤리。
Microfluidic technology is an efficient tool to control micro-scale phase interfaces precisely;therefore it is an important novel approach for design,preparation,and performance regulation and control of new functional materials with controllable micro-structures. In this paper,the controllable construction of two types of stable micro-scale phase interfaces with microfluidics is introduced. One type is the emulsion droplet system with enclosed liquid-liquid phase interface,and the other type is the laminar flow system with non-enclosed layered and annular liquid-liquid phase interface. The progress of preparation of three categories of functional materials with these two types of microfluidics-generated stable phase interface architectures as templates is reviewed , including fabrication of microspheres and microcapsules with emulsion droplets as templates,preparation of membranes in microchannels with layered laminar flow systems as templates,and synthesis of microfiber materials with annular laminar flow systems as templates. Microfluidic technology brings new opportunities for the realization of small-scale features and multi-functions of functional materials,ultra-thin membranes and ultra-fine fibers,and integration of materials and components. In the future,further in-depth and systematic understanding of design and regulation of the liquid-liquid phase interfaces as well as the regularities and mechanisms in the synthesis processes of functional materials should be emphasized.