光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2014年
9期
2413-2418
,共6页
孙向平%李国学%肖爱平%时红%王熠明%李扬阳
孫嚮平%李國學%肖愛平%時紅%王熠明%李颺暘
손향평%리국학%초애평%시홍%왕습명%리양양
红外光谱%元素分析%腐殖质%猪粪堆肥%玉米秸秆
紅外光譜%元素分析%腐殖質%豬糞堆肥%玉米秸稈
홍외광보%원소분석%부식질%저분퇴비%옥미갈간
FTIR%Element analysis%Humic substance%Pig manure composting%Maize straw
以猪粪和玉米秸秆为原料高温堆肥,试验设置三个不同处理:C/N 15,C/N 25,C/N 35。堆肥周期为120天,其中通风周期为30天,采用强制连续式通风。在第0,22,30,60,90,120天取样,利用元素分析和红外光谱法研究不同木质素添加量对堆肥胡敏酸(H A )的组分及分子结构的影响。研究表明堆肥胡敏酸C的变化主要集中在堆肥前30 d ,堆肥结束后,堆肥H A中O/C增大,H/C减小,N含量增加。不同处理之间低碳氮比(15)和高碳氮比(35)堆肥H A氧化程度要高于中碳氮比(25)。红外光谱吸收峰分析表明,不同木质素添加量处理堆肥过程中胡敏酸的红外光谱基本相似,但各峰吸收强度不同。研究表明堆肥腐熟化阶段更有利于堆肥H A中芳香性的增强。堆肥结束后,碳氮比15堆肥 H A中多糖、脂肪类成分减少,芳香结构成分增加,相比较碳氮比25和35,碳氮比15堆肥H A腐殖化程度更高,结构更稳定。
以豬糞和玉米秸稈為原料高溫堆肥,試驗設置三箇不同處理:C/N 15,C/N 25,C/N 35。堆肥週期為120天,其中通風週期為30天,採用彊製連續式通風。在第0,22,30,60,90,120天取樣,利用元素分析和紅外光譜法研究不同木質素添加量對堆肥鬍敏痠(H A )的組分及分子結構的影響。研究錶明堆肥鬍敏痠C的變化主要集中在堆肥前30 d ,堆肥結束後,堆肥H A中O/C增大,H/C減小,N含量增加。不同處理之間低碳氮比(15)和高碳氮比(35)堆肥H A氧化程度要高于中碳氮比(25)。紅外光譜吸收峰分析錶明,不同木質素添加量處理堆肥過程中鬍敏痠的紅外光譜基本相似,但各峰吸收彊度不同。研究錶明堆肥腐熟化階段更有利于堆肥H A中芳香性的增彊。堆肥結束後,碳氮比15堆肥 H A中多糖、脂肪類成分減少,芳香結構成分增加,相比較碳氮比25和35,碳氮比15堆肥H A腐殖化程度更高,結構更穩定。
이저분화옥미갈간위원료고온퇴비,시험설치삼개불동처리:C/N 15,C/N 25,C/N 35。퇴비주기위120천,기중통풍주기위30천,채용강제련속식통풍。재제0,22,30,60,90,120천취양,이용원소분석화홍외광보법연구불동목질소첨가량대퇴비호민산(H A )적조분급분자결구적영향。연구표명퇴비호민산C적변화주요집중재퇴비전30 d ,퇴비결속후,퇴비H A중O/C증대,H/C감소,N함량증가。불동처리지간저탄담비(15)화고탄담비(35)퇴비H A양화정도요고우중탄담비(25)。홍외광보흡수봉분석표명,불동목질소첨가량처리퇴비과정중호민산적홍외광보기본상사,단각봉흡수강도불동。연구표명퇴비부숙화계단경유리우퇴비H A중방향성적증강。퇴비결속후,탄담비15퇴비 H A중다당、지방류성분감소,방향결구성분증가,상비교탄담비25화35,탄담비15퇴비H A부식화정도경고,결구경은정。
Using pig manure and corn straw as raw materials for high-temperature composting ,setting three different treat-ments:C/N 15 ,C/N 25 ,and C/N 35 .Composting period is 120 days ,which contains 30 days for ventilation cycle by forced continuous ventilation .Sampled on 0 ,22 ,30 ,60 ,90 ,120th days ,they were analyzed by elemental analysis and IR spectrosco-py to study effect of different lignin content on compost humic acid (HA) composition and molecular structure .The results showed that the change in composting humic acid C focused on the first 30 days ,while after composting ,the O/C of compost HA increased ,H/C decreased ,and N content increased .Low C/N (15) and higher C/N ratio (35) had higher degree of oxida-tion than the C/N 25 in compost HA .FTIR indicated that the infrared spectrum shapes with different lignin content treatment are similar during the composting process ,but the peak intensity is obviously different .Research results proved that the compos-ting stage is more conducive to enhanced aromatic in compost HA .After composting ,C/N 15 had less polysaccharide and fat in-gredients and more aromatic structural components in compost HA ,compared with C/N 25 and 35 .In addition ,compost HA of C/N 15 had higher degree of humification and its structure was more stable .