分析化学
分析化學
분석화학
CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
2014年
9期
1252-1258
,共7页
胥月%汤纯静%黄宏%孙超群%张亚鲲%叶群峰%王爱军
胥月%湯純靜%黃宏%孫超群%張亞鯤%葉群峰%王愛軍
서월%탕순정%황굉%손초군%장아곤%협군봉%왕애군
碳量子点%绿色合成%苹果汁%汞离子检测
碳量子點%綠色閤成%蘋果汁%汞離子檢測
탄양자점%록색합성%평과즙%홍리자검측
Carbon quantum dots%Green synthesis%Apple juice%Mercury(Ⅱ) detection
本实验以苹果汁为原料,通过一步水热法合成得到了水溶性好及稳定性高的蓝色荧光碳量子点。研究发现 Hg2+对碳量子点荧光有良好的猝灭作用,从而建立了一种快速检测 Hg2+的新方法。实验发现在pH 7.0磷酸盐缓冲介质中碳量子点荧光猝灭强度与Hg2+浓度在5~100 nmol/L和1~50μmol/L范围内呈线性关系,检出限为2.3 nmol/L(S/N=3)。本方法可用于实际水样中Hg2+的测定。
本實驗以蘋果汁為原料,通過一步水熱法閤成得到瞭水溶性好及穩定性高的藍色熒光碳量子點。研究髮現 Hg2+對碳量子點熒光有良好的猝滅作用,從而建立瞭一種快速檢測 Hg2+的新方法。實驗髮現在pH 7.0燐痠鹽緩遲介質中碳量子點熒光猝滅彊度與Hg2+濃度在5~100 nmol/L和1~50μmol/L範圍內呈線性關繫,檢齣限為2.3 nmol/L(S/N=3)。本方法可用于實際水樣中Hg2+的測定。
본실험이평과즙위원료,통과일보수열법합성득도료수용성호급은정성고적람색형광탄양자점。연구발현 Hg2+대탄양자점형광유량호적졸멸작용,종이건립료일충쾌속검측 Hg2+적신방법。실험발현재pH 7.0린산염완충개질중탄양자점형광졸멸강도여Hg2+농도재5~100 nmol/L화1~50μmol/L범위내정선성관계,검출한위2.3 nmol/L(S/N=3)。본방법가용우실제수양중Hg2+적측정。
Fluorescent carbon quantum dots ( CQDs) were synthesized by one-step hydrothermal treatment of apple juice. Experiments showed that Hg2+could quench the fluorescence of the CQDs with specificity. Based on this phenomenon, a selective and sensitive sensor was constructed for Hg2+ detection. In a NaH2 PO4-Na2HPO4 buffer solution (pH 7. 0), their fluorescence intensity showed good linear relationship with the concentrations of Hg2+ from 5 to 100 nmol/L and 1 to 50 μmol/L, respectively, with the detection limit of 2. 3 nmol/L (S/N=3). Its practical application was further demonstrated by the detection of Hg2+ in real water samples.