粉末冶金材料科学与工程
粉末冶金材料科學與工程
분말야금재료과학여공정
POWDER METALLURGY MATERIALS SCIENCE AND ENGINEERING
2014年
4期
608-614
,共7页
熊志军%甘卫平%周健%罗林%黎应芬
熊誌軍%甘衛平%週健%囉林%黎應芬
웅지군%감위평%주건%라림%려응분
扩散法%丝网印刷%方块电阻%烧结工艺%光电转换效率
擴散法%絲網印刷%方塊電阻%燒結工藝%光電轉換效率
확산법%사망인쇄%방괴전조%소결공예%광전전환효솔
diffusion method%screen printing%sheet resistance%firing profile%photoelectric conversion efficiency
采用液态磷源扩散法,通过控制扩散工艺条件制备具有不同方块电阻的多晶体硅片,并采用丝网印刷烧结技术制备晶体硅太阳能电池片,研究方块电阻、正面细栅线电极宽度、主栅类型以及烧结工艺对晶硅太阳能电池的光电转换性能的影响。结果表明,在方块电阻为80?/□,栅线宽度为60μm条件下,采用三主栅时,多晶硅太阳能电池片的短路电流、开路电压及填充因子均较高,光电转换效率最优,达到16.931%。通过优化烧结工艺,选择峰值烧结温度为800℃,带速为660 cm/min以及升温速率为65.7℃/s,细栅线电极的致密度高,光电转换效率达到17.207%。
採用液態燐源擴散法,通過控製擴散工藝條件製備具有不同方塊電阻的多晶體硅片,併採用絲網印刷燒結技術製備晶體硅太暘能電池片,研究方塊電阻、正麵細柵線電極寬度、主柵類型以及燒結工藝對晶硅太暘能電池的光電轉換性能的影響。結果錶明,在方塊電阻為80?/□,柵線寬度為60μm條件下,採用三主柵時,多晶硅太暘能電池片的短路電流、開路電壓及填充因子均較高,光電轉換效率最優,達到16.931%。通過優化燒結工藝,選擇峰值燒結溫度為800℃,帶速為660 cm/min以及升溫速率為65.7℃/s,細柵線電極的緻密度高,光電轉換效率達到17.207%。
채용액태린원확산법,통과공제확산공예조건제비구유불동방괴전조적다정체규편,병채용사망인쇄소결기술제비정체규태양능전지편,연구방괴전조、정면세책선전겁관도、주책류형이급소결공예대정규태양능전지적광전전환성능적영향。결과표명,재방괴전조위80?/□,책선관도위60μm조건하,채용삼주책시,다정규태양능전지편적단로전류、개로전압급전충인자균교고,광전전환효솔최우,체도16.931%。통과우화소결공예,선택봉치소결온도위800℃,대속위660 cm/min이급승온속솔위65.7℃/s,세책선전겁적치밀도고,광전전환효솔체도17.207%。
Multicrystalline silicons with different sheet resistance were prepared using liquid phosphorus source diffusion method and controlling the process conditions. Crystalline silicon solar cells were made by screen printing and firing technology. The effects of sheet resistance, front side electrode gridline width, busbar design types and firing profiles on the photoelectric conversion performance parameters were investigated. The results show that, when the square sheet resistance is 80?/□and the gridline design width is 60μm under the condition of three busbars, the higher short circuit current, open circuit voltage and fill factors of crystalline silicon solar cells can be obtained, and the photoelectric conversion efficiency is the best reaching up to 16.931%. By optimizing the firing profiles, the density of fine gridline electrode is the high and the photoelectric conversion efficiency can be improved to 17.207% when the peak firing temperature is 800℃, the belt speed is 660 cm/min and heating rate is 65.7℃/s.