粉末冶金材料科学与工程
粉末冶金材料科學與工程
분말야금재료과학여공정
POWDER METALLURGY MATERIALS SCIENCE AND ENGINEERING
2014年
4期
546-552
,共7页
朱胜%刘玉项%王晓明%韩国峰
硃勝%劉玉項%王曉明%韓國峰
주성%류옥항%왕효명%한국봉
ZM5镁合金%超音速微粒沉积%Al-Si涂层%封孔处理%耐蚀性
ZM5鎂閤金%超音速微粒沉積%Al-Si塗層%封孔處理%耐蝕性
ZM5미합금%초음속미립침적%Al-Si도층%봉공처리%내식성
ZM5 magnesium%supersonic micro-particles deposition%Al-Si coating%sealing treatment%corrosion resistance
为提高镁合金的耐蚀性能,采用超音速微粒沉积技术在ZM5基体上制备Al-Si防护涂层。采用环氧面漆对涂层进行封孔处理,采用电化学方法和中性盐雾实验对镁合金基体、涂层及涂层封孔后的抗腐蚀性能进行测试。结果表明:防护涂层致密,缺陷少,可显著提高ZM5镁合金的耐蚀性能;腐蚀电流密度比基体降低2~3个数量级,阻抗模值提高2个数量级,而涂层封孔后耐蚀性能进一步提高。相比镁合金24 h严重腐蚀,涂层中性盐雾实验1000 h仅轻微腐蚀,腐蚀造成的质量损耗较小,封孔后涂层未见明显腐蚀,可为镁合金提供长效防护。
為提高鎂閤金的耐蝕性能,採用超音速微粒沉積技術在ZM5基體上製備Al-Si防護塗層。採用環氧麵漆對塗層進行封孔處理,採用電化學方法和中性鹽霧實驗對鎂閤金基體、塗層及塗層封孔後的抗腐蝕性能進行測試。結果錶明:防護塗層緻密,缺陷少,可顯著提高ZM5鎂閤金的耐蝕性能;腐蝕電流密度比基體降低2~3箇數量級,阻抗模值提高2箇數量級,而塗層封孔後耐蝕性能進一步提高。相比鎂閤金24 h嚴重腐蝕,塗層中性鹽霧實驗1000 h僅輕微腐蝕,腐蝕造成的質量損耗較小,封孔後塗層未見明顯腐蝕,可為鎂閤金提供長效防護。
위제고미합금적내식성능,채용초음속미립침적기술재ZM5기체상제비Al-Si방호도층。채용배양면칠대도층진행봉공처리,채용전화학방법화중성염무실험대미합금기체、도층급도층봉공후적항부식성능진행측시。결과표명:방호도층치밀,결함소,가현저제고ZM5미합금적내식성능;부식전류밀도비기체강저2~3개수량급,조항모치제고2개수량급,이도층봉공후내식성능진일보제고。상비미합금24 h엄중부식,도층중성염무실험1000 h부경미부식,부식조성적질량손모교소,봉공후도층미견명현부식,가위미합금제공장효방호。
In order to improve anti-corrosion properties of magnesium alloy, Al-Si coating on the ZM5 magnesium alloy was prepared by micro-supersonic particles deposition. The electrochemical method and the neural salt-spray test were used to evaluate the corrosion resistance of the magnesium substrate, Al-Si coating and the coating with sealing specimens. The results indicate that the Al-Si coating is dense and less of defects, and it can improve the corrosion resistance of ZM5 substrate obviously. The corrosion current density decreases 2~3 orders of magnitude and the impedance modules increases 2 orders of magnitude in contrast to magnesium, and the coatings with sealing can improve corrosion resistance of substrate further. Compared with the severe corrosion of magnesium at the 24 h neural salt-spray test, the coating is just corroding slightly at 1 000 h and the mass loss of specimens is little, and the corrosion of coating with sealing is not observed obviously, so the coating and the sealing treatment can make a long-life protection for ZM5.