地球化学
地毬化學
지구화학
GEOCHIMICA
2014年
5期
477-488
,共12页
吴小奇%刘全有%陶小晚%胡国艺
吳小奇%劉全有%陶小晚%鬍國藝
오소기%류전유%도소만%호국예
天然气%地球化学特征%哈拉哈塘凹陷%塔里木盆地
天然氣%地毬化學特徵%哈拉哈塘凹陷%塔裏木盆地
천연기%지구화학특정%합랍합당요함%탑리목분지
natural gas%geochemical characteristics%Halahatang Sag%Tarim Basin
哈拉哈塘凹陷位于塔里木盆地塔北隆起中部,具有良好的石油地质条件,是近期油气勘探的重点区带。天然气地球化学特征研究表明,该区天然气干燥系数较低,表现出典型湿气的特征,普遍含有微量的H2S;烷烃气δ13C1和δ13C2值分别为-50.5‰~-42.6‰和-40.2‰~-35.5‰,δD1值介于-262‰~-156‰之间,碳氢同位素系列表现出典型正序特征; C7轻烃组成具有正庚烷优势分布, C5~7轻烃组成以正构和异构烷烃为主。哈拉哈塘凹陷及周缘奥陶系天然气均为海相油型气,既有干酪根裂解气,也有原油裂解气,其中哈拉哈塘天然气中混入了相当比例的原油裂解初期形成的湿气,主要来自于南部阿满过渡带地区的中上奥陶统烃源岩,天然气中具有高δ13C值特征的CO2主要来自碳酸盐岩储层在酸性地层水作用下发生的溶蚀, H2S主要源自含硫化合物的热裂解。其中天然气发生的同位素部分倒转主要源自原油伴生气与原油裂解气的混合。
哈拉哈塘凹陷位于塔裏木盆地塔北隆起中部,具有良好的石油地質條件,是近期油氣勘探的重點區帶。天然氣地毬化學特徵研究錶明,該區天然氣榦燥繫數較低,錶現齣典型濕氣的特徵,普遍含有微量的H2S;烷烴氣δ13C1和δ13C2值分彆為-50.5‰~-42.6‰和-40.2‰~-35.5‰,δD1值介于-262‰~-156‰之間,碳氫同位素繫列錶現齣典型正序特徵; C7輕烴組成具有正庚烷優勢分佈, C5~7輕烴組成以正構和異構烷烴為主。哈拉哈塘凹陷及週緣奧陶繫天然氣均為海相油型氣,既有榦酪根裂解氣,也有原油裂解氣,其中哈拉哈塘天然氣中混入瞭相噹比例的原油裂解初期形成的濕氣,主要來自于南部阿滿過渡帶地區的中上奧陶統烴源巖,天然氣中具有高δ13C值特徵的CO2主要來自碳痠鹽巖儲層在痠性地層水作用下髮生的溶蝕, H2S主要源自含硫化閤物的熱裂解。其中天然氣髮生的同位素部分倒轉主要源自原油伴生氣與原油裂解氣的混閤。
합랍합당요함위우탑리목분지탑북륭기중부,구유량호적석유지질조건,시근기유기감탐적중점구대。천연기지구화학특정연구표명,해구천연기간조계수교저,표현출전형습기적특정,보편함유미량적H2S;완경기δ13C1화δ13C2치분별위-50.5‰~-42.6‰화-40.2‰~-35.5‰,δD1치개우-262‰~-156‰지간,탄경동위소계렬표현출전형정서특정; C7경경조성구유정경완우세분포, C5~7경경조성이정구화이구완경위주。합랍합당요함급주연오도계천연기균위해상유형기,기유간락근렬해기,야유원유렬해기,기중합랍합당천연기중혼입료상당비례적원유렬해초기형성적습기,주요래자우남부아만과도대지구적중상오도통경원암,천연기중구유고δ13C치특정적CO2주요래자탄산염암저층재산성지층수작용하발생적용식, H2S주요원자함류화합물적열렬해。기중천연기발생적동위소부분도전주요원자원유반생기여원유렬해기적혼합。
Halahatang Sag is located at the central part of the Tabei Uplift, Tarim Basin with favorable petroleum geological condition. It is an important exploration area. Geochemical characteristics of natural gas indicate that the natural gas displays low dryness indexes with trace-amount of H2S. Theδ13C1,δ13C2 andδD1 values of natural gas are in the ranges of -50.5‰--42.6‰, -40.2‰--35.5‰ and -262‰--156‰, respectively, with positive carbon and hydrogen isotopic series. The C7 light hydrocarbons are dominated by n-heptane with C5~7 dominated by normal alkanes and isoalkanes. The Ordovician-reservoired gases in Halahatang Sag and the adjacent area are marine oil-type gas from both kerogen cracking and oil cracking. The gases from Halahatang Sag include a significant proportion of wet gas formed in the early stage of oil cracking. They were mainly derived from the Middle-Upper Ordovician source rocks in the Awati-Manjiaer transitional zone. CO2 with highδ13C values in the Ordovician-reservoired gas was mainly derived from the dissolution of carbonate reservoirs under acidic formation water, with the H2S from thermal decomposition of sulfides. The partial isotopic reversal of gases originated mainly from the mixing of oil-associated gas and oil-cracking gas.