石油炼制与化工
石油煉製與化工
석유련제여화공
PETROLEUM PROCESSING AND PETROCHEMICALS
2014年
9期
20-23
,共4页
黄娟%任波%李本高%杨祖国
黃娟%任波%李本高%楊祖國
황연%임파%리본고%양조국
稠油%催化改质%降黏%机理
稠油%催化改質%降黏%機理
주유%최화개질%강점%궤리
heavy oil%catalytic modification%viscosity reduction%mechanism
在中国石化西北油田分公司中型试验装置上采用中国石化石油化工科学研究院研制的催化降黏剂对塔河 TH12196单井稠油的降黏作用进行了考察。结果表明:当反应温度为160℃、反应时间为6 h、催化降黏剂加入量(w)为1.5%时,稠油降黏率达到54.5%;催化降黏率较热降黏率高51.4百分点,且降黏后稠油中重质组分含量减少,轻质组分含量增加;在稠油催化改质处理过程中,分子中较弱的化学键发生断裂,从而使稠油分子聚集体变小,产生不可逆降黏作用。
在中國石化西北油田分公司中型試驗裝置上採用中國石化石油化工科學研究院研製的催化降黏劑對塔河 TH12196單井稠油的降黏作用進行瞭攷察。結果錶明:噹反應溫度為160℃、反應時間為6 h、催化降黏劑加入量(w)為1.5%時,稠油降黏率達到54.5%;催化降黏率較熱降黏率高51.4百分點,且降黏後稠油中重質組分含量減少,輕質組分含量增加;在稠油催化改質處理過程中,分子中較弱的化學鍵髮生斷裂,從而使稠油分子聚集體變小,產生不可逆降黏作用。
재중국석화서북유전분공사중형시험장치상채용중국석화석유화공과학연구원연제적최화강점제대탑하 TH12196단정주유적강점작용진행료고찰。결과표명:당반응온도위160℃、반응시간위6 h、최화강점제가입량(w)위1.5%시,주유강점솔체도54.5%;최화강점솔교열강점솔고51.4백분점,차강점후주유중중질조분함량감소,경질조분함량증가;재주유최화개질처리과정중,분자중교약적화학건발생단렬,종이사주유분자취집체변소,산생불가역강점작용。
The field test for viscosity reduction of Tahe TH12196 heavy oil by hydrothermal catalyt-ic process was conducted in the pilot plant of Northwest Oilfield Company,SINOPEC using a catalytic viscosity reducer developed by Research Institute of Petroleum Processing. The results show that the viscosity of Tahe oil is reduced by 54.5% after catalytic modification at the conditions of reaction time of 6 h,160 ℃ and the viscosity reducer dosage of 1.5%,51.4% more than that of hydrothermal method, while similar to the results of laboratory. After the modification,the heavy components are decreased and the light ones are increased. The breakage of weaker chemical bond between molecules leads the composition changes of heavy oil,resulting in smaller aggregations and irreversible viscosity reduction.