火炸药学报
火炸藥學報
화작약학보
CHINESE JOURNAL OF EXPLOSIVES & PROPELLANTS
2014年
4期
87-90
,共4页
陈斌%刘波%姬月萍%王琼林%高福磊%魏伦
陳斌%劉波%姬月萍%王瓊林%高福磊%魏倫
진빈%류파%희월평%왕경림%고복뢰%위륜
应用化学%消焰剂%二羟基乙二肟钾%DHGK%发射药%枪口烟焰
應用化學%消燄劑%二羥基乙二肟鉀%DHGK%髮射藥%鎗口煙燄
응용화학%소염제%이간기을이우갑%DHGK%발사약%창구연염
applied chemistry%flame inhibitor%potassium dihydroxyglyxime%DHGK%gun propellant%muzzle flame and smoke
以盐酸羟胺为原料,通过肟化成盐得到二羟基乙二肟钾(DHGK),采用红外光谱、元素分析、核磁共振对其结构进行了表征。制备了含 DHGK 的发射装药,采用高速摄影、烟箱法和氧弹法测试了其枪口烟焰及燃烧残渣,用5.8 mm 内弹道试验研究了其内弹道性能。结果表明,用 DHGK 替代制式消焰剂硫酸钾和硝酸钾,可使枪口火焰面积减少70.7%,火焰温度降低400 K,枪口烟雾较小,燃烧残渣量减小,表明 DHGK 有良好的抑制枪口烟焰效果。添加 DHGK 的发射装药能够提高弹丸的初速,并且有较好的内弹道稳定性。
以鹽痠羥胺為原料,通過肟化成鹽得到二羥基乙二肟鉀(DHGK),採用紅外光譜、元素分析、覈磁共振對其結構進行瞭錶徵。製備瞭含 DHGK 的髮射裝藥,採用高速攝影、煙箱法和氧彈法測試瞭其鎗口煙燄及燃燒殘渣,用5.8 mm 內彈道試驗研究瞭其內彈道性能。結果錶明,用 DHGK 替代製式消燄劑硫痠鉀和硝痠鉀,可使鎗口火燄麵積減少70.7%,火燄溫度降低400 K,鎗口煙霧較小,燃燒殘渣量減小,錶明 DHGK 有良好的抑製鎗口煙燄效果。添加 DHGK 的髮射裝藥能夠提高彈汍的初速,併且有較好的內彈道穩定性。
이염산간알위원료,통과우화성염득도이간기을이우갑(DHGK),채용홍외광보、원소분석、핵자공진대기결구진행료표정。제비료함 DHGK 적발사장약,채용고속섭영、연상법화양탄법측시료기창구연염급연소잔사,용5.8 mm 내탄도시험연구료기내탄도성능。결과표명,용 DHGK 체대제식소염제류산갑화초산갑,가사창구화염면적감소70.7%,화염온도강저400 K,창구연무교소,연소잔사량감소,표명 DHGK 유량호적억제창구연염효과。첨가 DHGK 적발사장약능구제고탄환적초속,병차유교호적내탄도은정성。
Potassium dihydroxyglyxime (DHGK)was synthesized via oximation reaction and salt formation using hydroxyamine hydrochloride as a staring material.The structure of DHGK was characterized by IR,NMR and ele-mental analysis.The gun propellant charge containing DHGK was prepared.The muzzle flame and smoke and com-bustion residue of gun propellant were measured by high speed photography method,smoke box method and oxygen bomb method,and the interior ballistic performance was investigated by the means of 5.8mm interior ballistic test. The results show that replacing the common flame inhibitor K2 SO4 and KNO3 with DHGK makes the flame area de-crease by 70.7%,flame temperature reduce by 400 K,muzzle flame and smoke and combustion residue decrease,re-vealing that DHGK has better effect on the decrease of muzzle flame and smoke.The gun propellant charge adding DHGK can enhance the muzzle velocity and has good interior ballistic stability.