人民黄河
人民黃河
인민황하
Yellow River
2014年
9期
86-88,91
,共4页
孙亚乔%段磊%窦琳%乔晓霞%申圆圆
孫亞喬%段磊%竇琳%喬曉霞%申圓圓
손아교%단뢰%두림%교효하%신원원
表层沉积物%重金属%赋存形态%转化机理%客水
錶層沉積物%重金屬%賦存形態%轉化機理%客水
표층침적물%중금속%부존형태%전화궤리%객수
sediments%heavy metals%chemical speciation%transformation%water-received
通过河床表层沉积物重金属释放实验,分析并揭示了受客水后河床表层沉积物中重金属Co、Cr、Mn、Mo、Pb、V的赋存形态转化机理。结果表明:受水区的环境条件(pH值、Eh值等)变化、沉积物理化性质变化和环境中微生物的作用,重金属生物有效态及残渣态之间的相互转化,改变了重金属的生物有效性,在受客水过程中受溶解沉淀、吸附解吸、氧化还原和离子交换等地球化学作用的影响,河床沉积物中重金属发生迁移转化,在不断受水条件下河床沉积物中重金属不断释放,沉积物不断净化。
通過河床錶層沉積物重金屬釋放實驗,分析併揭示瞭受客水後河床錶層沉積物中重金屬Co、Cr、Mn、Mo、Pb、V的賦存形態轉化機理。結果錶明:受水區的環境條件(pH值、Eh值等)變化、沉積物理化性質變化和環境中微生物的作用,重金屬生物有效態及殘渣態之間的相互轉化,改變瞭重金屬的生物有效性,在受客水過程中受溶解沉澱、吸附解吸、氧化還原和離子交換等地毬化學作用的影響,河床沉積物中重金屬髮生遷移轉化,在不斷受水條件下河床沉積物中重金屬不斷釋放,沉積物不斷淨化。
통과하상표층침적물중금속석방실험,분석병게시료수객수후하상표층침적물중중금속Co、Cr、Mn、Mo、Pb、V적부존형태전화궤리。결과표명:수수구적배경조건(pH치、Eh치등)변화、침적물이화성질변화화배경중미생물적작용,중금속생물유효태급잔사태지간적상호전화,개변료중금속적생물유효성,재수객수과정중수용해침정、흡부해흡、양화환원화리자교환등지구화학작용적영향,하상침적물중중금속발생천이전화,재불단수수조건하하상침적물중중금속불단석방,침적물불단정화。
The chemical speciation transformation of heavy metals Co、Cr、Mn、Mo、Pb and V in sediments had been investigated through heavy met-als release experiment. The results show that the biologically effective of heavy metal have been changed due to the change of the water environmen-tal conditions (pH value and Eh value),physical and chemical properties of sediments,and action of microorganisms in sedimentary environment. For the geochemical role of dissolution and precipitation,adsorption and desorption,oxidation and reduction,and ion exchange,the heavy metal in sediments are migration and transformation. So,the heavy metal in sediments is releasing after water-received,and the sediment environment is pu-rifying continuously.