辽宁师范大学学报(自然科学版)
遼寧師範大學學報(自然科學版)
료녕사범대학학보(자연과학판)
JOURNAL OF LIAONING NORMAL UNIVERSITY(NATURAL SCIENCE)
2014年
3期
385-388
,共4页
陈立东%于博浩%李传鹏%孙胜男%朱江%李禹蒙%宋鹏月%王旭阳%杨晓宇%姜春杰
陳立東%于博浩%李傳鵬%孫勝男%硃江%李禹矇%宋鵬月%王旭暘%楊曉宇%薑春傑
진립동%우박호%리전붕%손성남%주강%리우몽%송붕월%왕욱양%양효우%강춘걸
磷钼钒酸%纳米晶体%ZSM-5沸石%FCC汽油%加氢改质
燐鉬釩痠%納米晶體%ZSM-5沸石%FCC汽油%加氫改質
린목범산%납미정체%ZSM-5비석%FCC기유%가경개질
phosphovanadomolybdic acid%nanocrystalline%HZSM-5 zeolite%FCC gasoline%hydrofining
以目前国际上两大研究热点杂多酸和纳米晶沸石为研究的活性组分和载体,采用浸渍法制备了镍盐(以NiO计2.5%)促进的单钒取代磷钼酸(10%)基纳米HZSM -5复合固体酸催化剂,IR和UV-Raman表征的结果显示单钒取代磷钼酸以Keggin结构存在于载体纳米晶HZSM-5上.在连续固定床反应器上以劣质催化裂化汽油加氢精制为探针反应评价了制备催化剂的反应性能.评价结果表明,在温和的反应条件下[汽油,2.2 mL/h ;WHSV ,0.8 h-1;反应温度285℃;VH2∶V油=300;系统压力2.1 MPa;催化剂装填量2.1 g ],产物组成经碱洗和乙醇调和后可达到93#汽油国V排放标准,催化剂显示出了良好的低温芳构化、加氢脱硫反应性能和催化活性的稳定性.催化剂具有可循环使用、制备方法简单和加氢精制活性高等优势,具有一定应用前景.
以目前國際上兩大研究熱點雜多痠和納米晶沸石為研究的活性組分和載體,採用浸漬法製備瞭鎳鹽(以NiO計2.5%)促進的單釩取代燐鉬痠(10%)基納米HZSM -5複閤固體痠催化劑,IR和UV-Raman錶徵的結果顯示單釩取代燐鉬痠以Keggin結構存在于載體納米晶HZSM-5上.在連續固定床反應器上以劣質催化裂化汽油加氫精製為探針反應評價瞭製備催化劑的反應性能.評價結果錶明,在溫和的反應條件下[汽油,2.2 mL/h ;WHSV ,0.8 h-1;反應溫度285℃;VH2∶V油=300;繫統壓力2.1 MPa;催化劑裝填量2.1 g ],產物組成經堿洗和乙醇調和後可達到93#汽油國V排放標準,催化劑顯示齣瞭良好的低溫芳構化、加氫脫硫反應性能和催化活性的穩定性.催化劑具有可循環使用、製備方法簡單和加氫精製活性高等優勢,具有一定應用前景.
이목전국제상량대연구열점잡다산화납미정비석위연구적활성조분화재체,채용침지법제비료얼염(이NiO계2.5%)촉진적단범취대린목산(10%)기납미HZSM -5복합고체산최화제,IR화UV-Raman표정적결과현시단범취대린목산이Keggin결구존재우재체납미정HZSM-5상.재련속고정상반응기상이렬질최화열화기유가경정제위탐침반응평개료제비최화제적반응성능.평개결과표명,재온화적반응조건하[기유,2.2 mL/h ;WHSV ,0.8 h-1;반응온도285℃;VH2∶V유=300;계통압력2.1 MPa;최화제장전량2.1 g ],산물조성경감세화을순조화후가체도93#기유국V배방표준,최화제현시출료량호적저온방구화、가경탈류반응성능화최화활성적은정성.최화제구유가순배사용、제비방법간단화가경정제활성고등우세,구유일정응용전경.
The two international hot issues ,the heteropoly acid and nanocrystalline zeolite were cho-sen as active components and support .FCC gasoline hydrotreating catalyst was prepared through im-pregnating nanocrystalline HZSM -5 zeolite into nickel nitrate and phosphovanadomolybdic acid .Af-ter calcination the Keggin type structure was preserved in hydrotreating catalyst confirmed by IR and UV-Raman spectrum .The catalyst was examined in the reactions of FCC gasoline hydrodesulfuriza-tion which were performed in a fixed-bed continuous-flow stainless steel catalytic reactor under less severe reaction conditions (under 285 ℃ in a pressure of 2 .0 M Pa) .T he 93# clean gasoline products according with the National V standards had been obtained after caustic washing and ethanol blen-ded .This catalyst may be applied in the field of gasoline hydrodesulfurization for the high activity in reducing olefins ,the activity of atomization and the hydrodesulfurization activity are determined .