CAJ | 학술논문

以酚锂作为副反应抑制剂,以正丁基锂或1,1-二苯基乙烯盖帽的正丁基锂为引发剂,通过顺次添加单体的方法,合成了结构明确的聚异戊二烯-b-聚甲基丙烯酸甲酯( PI-b-PMMA)和聚甲基丙烯酸正丁酯-b-聚甲基丙烯酸甲酯(PBMA-b-PMMA)2种嵌段聚合物.嵌段聚合反应中甲基丙烯酸甲酯(MMA)的转化率均高于90%,通过核磁图谱计算的链节摩尔比与理论设计值吻合. PI-b-PMMA和PBMA-b-PMMA的分子量分别达到4×104和1.6×104.在环己烷中,通过顺次添加单体的方法,合成了结构明确的聚苯乙烯-b-聚异戊二烯-b-聚甲基丙烯酸甲酯( PS-b-PI-b-PMMA)三嵌段共聚物,各单体的转化率均达到100%,并且产物中的链节摩尔比和理论设计值一致,最终产物的分子量达到7.4×104,分子量分布仅为1.28,为极性三嵌段热塑性弹性体以及有机玻璃透明增韧剂的工业化奠定了基础.
이분리작위부반응억제제,이정정기리혹1,1-이분기을희개모적정정기리위인발제,통과순차첨가단체적방법,합성료결구명학적취이무이희-b-취갑기병희산갑지( PI-b-PMMA)화취갑기병희산정정지-b-취갑기병희산갑지(PBMA-b-PMMA)2충감단취합물.감단취합반응중갑기병희산갑지(MMA)적전화솔균고우90%,통과핵자도보계산적련절마이비여이론설계치문합. PI-b-PMMA화PBMA-b-PMMA적분자량분별체도4×104화1.6×104.재배기완중,통과순차첨가단체적방법,합성료결구명학적취분을희-b-취이무이희-b-취갑기병희산갑지( PS-b-PI-b-PMMA)삼감단공취물,각단체적전화솔균체도100%,병차산물중적련절마이비화이론설계치일치,최종산물적분자량체도7.4×104,분자량분포부위1.28,위겁성삼감단열소성탄성체이급유궤파리투명증인제적공업화전정료기출.
Well-defined block copolymers polyisoprene-b-poly( methyl methacrylate) ( PI-b-PMMA) and poly ( butyl methacrylate )-b-poly ( methyl methacrylate ) ( PBMA-b-PMMA were synthesized in THF initiated by n-BuLi and DPHLi with the addition of P-Complex. The polymerizations were carried out under the conditions which could be achieved in industry through adding monomers by sequence. The conversion of MMA was higher than 90% both in PI-b-PMMA and PBMA-b-PMMA, and the molar ratios of each segment in block copolymers detected by 1 H NMR fit to those calculated. The Mn of PI-b-PMMA and PBMA-b-PMMA were 4. 0×104 and 1. 6 × 104, respectively. Well-defined triblock polymer PS-b-PI-b-PMMA was synthesized in cyclohexane under the condition which could be achieved in industry. The conversions of monomers were all completed, and the molar ratio in the final triblock polymer was consistent to the one calculated. The final Mn was 7. 4×104, and the molecular weight distribution(MWD) was only 1. 28.