广州大学学报(自然科学版)
廣州大學學報(自然科學版)
엄주대학학보(자연과학판)
JOURNAL OF GUANGZHOU UNIVERSITY(NATURAL SCIENCE EDITION)
2014年
3期
40-46
,共7页
化学分析%回收率%不确定度%公式%探讨
化學分析%迴收率%不確定度%公式%探討
화학분석%회수솔%불학정도%공식%탐토
chemical analysis%recovery rate%uncertainty%formula%thinking
以化学测量回收率定义及其过程特点为依据,分析了3种流行公式的适用性,认为它们都不是普适公式而各有其适用条件,随意套用获得的结果可靠性较低。思考了合理评估方法,认为化学回收率不是一个直接测量量,其不确定度是各复合因素合成的结果;平均回收率不确定度只是回收率总不确定度中的一个重复性分量,只有当它占绝对优势时才可代表回收率总不确定度;遵循过程与模型的评估原则可获得针对性强、可靠程度高的评估结果。
以化學測量迴收率定義及其過程特點為依據,分析瞭3種流行公式的適用性,認為它們都不是普適公式而各有其適用條件,隨意套用穫得的結果可靠性較低。思攷瞭閤理評估方法,認為化學迴收率不是一箇直接測量量,其不確定度是各複閤因素閤成的結果;平均迴收率不確定度隻是迴收率總不確定度中的一箇重複性分量,隻有噹它佔絕對優勢時纔可代錶迴收率總不確定度;遵循過程與模型的評估原則可穫得針對性彊、可靠程度高的評估結果。
이화학측량회수솔정의급기과정특점위의거,분석료3충류행공식적괄용성,인위타문도불시보괄공식이각유기괄용조건,수의투용획득적결과가고성교저。사고료합리평고방법,인위화학회수솔불시일개직접측량량,기불학정도시각복합인소합성적결과;평균회수솔불학정도지시회수솔총불학정도중적일개중복성분량,지유당타점절대우세시재가대표회수솔총불학정도;준순과정여모형적평고원칙가획득침대성강、가고정도고적평고결과。
Based on the definition and process feature of recovery percentage , the present authors analyzed the applicability of three popular formulas , it is deemed that these formulas are not universally used while each has specific conditions of application , and the reliability of results obtained by indiscriminately using the formulas is low.The reasonable assessment method is thought aabout , it is found that the recovery percentage in chemical analysis is not a direct measuring quantity , the uncertainty of recovery percentage should be the synthetic result of some composite factors , and the uncertainty of average recovery percentage is just the repetitive components in overall uncertainty of recovery percentage , and average recovery percentage can represent the overall uncer-tainty of recovery percentage only when it is dominated .It is recommended that by complying with the process and the principles of evaluating model , a higher reliability of the result can be obtained .