辽宁石油化工大学学报
遼寧石油化工大學學報
료녕석유화공대학학보
JOURNAL OF LIAONING UNIVERSITY OF PETROLEUM & CHEMICAL TECHNOLOGY
2014年
4期
18-21
,共4页
苏婷婷%游春玲%臧立桃%范春宇%姜恒%宫红
囌婷婷%遊春玲%臧立桃%範春宇%薑恆%宮紅
소정정%유춘령%장립도%범춘우%강항%궁홍
铌酸钾%改进固相法%光催化%亚甲基蓝%低温合成
鈮痠鉀%改進固相法%光催化%亞甲基藍%低溫閤成
니산갑%개진고상법%광최화%아갑기람%저온합성
Potassium niobate%Improved solid-state method%Photocatalysis%Methylene Blue%Low-temperature synthesis
采用草酸铌和KOH 为原料,加入少许水研磨至干燥后得到前躯体,前躯体在500℃焙烧3 h合成了铌酸钾粉末。红外光谱分析结果表明,在研磨过程中,原料之间发生了离子交换作用,有 NH3被释放出来。以铌酸钾粉末为光催化剂,在紫外灯照射下,对亚甲基蓝溶液进行光催化降解实验,结果表明,光催化3h后,亚甲基蓝的降解率达到90%。
採用草痠鈮和KOH 為原料,加入少許水研磨至榦燥後得到前軀體,前軀體在500℃焙燒3 h閤成瞭鈮痠鉀粉末。紅外光譜分析結果錶明,在研磨過程中,原料之間髮生瞭離子交換作用,有 NH3被釋放齣來。以鈮痠鉀粉末為光催化劑,在紫外燈照射下,對亞甲基藍溶液進行光催化降解實驗,結果錶明,光催化3h後,亞甲基藍的降解率達到90%。
채용초산니화KOH 위원료,가입소허수연마지간조후득도전구체,전구체재500℃배소3 h합성료니산갑분말。홍외광보분석결과표명,재연마과정중,원료지간발생료리자교환작용,유 NH3피석방출래。이니산갑분말위광최화제,재자외등조사하,대아갑기람용액진행광최화강해실험,결과표명,광최화3h후,아갑기람적강해솔체도90%。
Potassium Niobate was obtained by grinding the mixture of niobium formate and potassium hydroxide and small amount of water,then dried at room temperature,and finally calcined at 500 ℃ for 3 h .It can be seen from the Infrared spectroscopy that an ion-exchange reaction occurred and NH3 was released during grinding.As-synthesized potassium niobate powders were used to degrade methylene blue solution under irradiation of UV,and found that the catalyst showed better photocatalytic properties,and the degradation ratio reaches to 90% after 3 h reaction.