北京科技大学学报
北京科技大學學報
북경과기대학학보
JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING
2014年
9期
1166-1173
,共8页
宁晓宇%薛庆国%王广%丁闪%佘雪峰%王静松
寧曉宇%薛慶國%王廣%丁閃%佘雪峰%王靜鬆
저효우%설경국%왕엄%정섬%사설봉%왕정송
球团%直接还原%熔分%渗碳
毬糰%直接還原%鎔分%滲碳
구단%직접환원%용분%삼탄
ore pellets%direct reduction%melting%carburization
为了探究含碳球团还原熔分机理,将分析纯的 Fe2 O3、氧化物和不同还原剂固结成球并进行等温还原实验,研究了温度、还原时间、配碳量、还原剂种类等条件对球团还原熔分行为的影响.进一步采用 X 射线衍射、扫描电子显微镜等手段表征了含碳球团在不同还原时间的微观结构及物相变化.实验结果表明:焙烧温度过低或过高含碳球团都不能良好熔分,配碳量增加可以提高球团还原和熔分速率,适宜的温度、碳氧摩尔比、还原剂分别是1400℃、1.2和煤粉.含碳球团还原熔分包括直接还原反应、间接还原反应、碳的气化反应、渗碳反应和铁的熔化反应,最后实现渣铁分离.
為瞭探究含碳毬糰還原鎔分機理,將分析純的 Fe2 O3、氧化物和不同還原劑固結成毬併進行等溫還原實驗,研究瞭溫度、還原時間、配碳量、還原劑種類等條件對毬糰還原鎔分行為的影響.進一步採用 X 射線衍射、掃描電子顯微鏡等手段錶徵瞭含碳毬糰在不同還原時間的微觀結構及物相變化.實驗結果錶明:焙燒溫度過低或過高含碳毬糰都不能良好鎔分,配碳量增加可以提高毬糰還原和鎔分速率,適宜的溫度、碳氧摩爾比、還原劑分彆是1400℃、1.2和煤粉.含碳毬糰還原鎔分包括直接還原反應、間接還原反應、碳的氣化反應、滲碳反應和鐵的鎔化反應,最後實現渣鐵分離.
위료탐구함탄구단환원용분궤리,장분석순적 Fe2 O3、양화물화불동환원제고결성구병진행등온환원실험,연구료온도、환원시간、배탄량、환원제충류등조건대구단환원용분행위적영향.진일보채용 X 사선연사、소묘전자현미경등수단표정료함탄구단재불동환원시간적미관결구급물상변화.실험결과표명:배소온도과저혹과고함탄구단도불능량호용분,배탄량증가가이제고구단환원화용분속솔,괄의적온도、탄양마이비、환원제분별시1400℃、1.2화매분.함탄구단환원용분포괄직접환원반응、간접환원반응、탄적기화반응、삼탄반응화철적용화반응,최후실현사철분리.
To explore the mechanism of reduction and melting-separation in carbon-bearing pellets, cold-bound pellets were made of analytically pure Fe2 O3 , oxides, and different reductants, and their isothermal reduction experiment was carried out. The influences of reduction parameters, such as temperature, reduction time, carbon/ oxygen mole ratio, and type of reductants, on the metallization degree and melting behavior were discussed on the basis of experimental data. The microstructure and phase transformation of the pel-lets were characterized by X-ray diffraction and scanning electron microscopy. It is found that the pellets cannot be molten well at too low or too high temperature. An increase in carbon/ oxygen mole ratio can improve the reduction and melting rate of the pellets. The ap-propriate temperature, carbon/ oxygen mole ratio, and reducing agent are 1400 ℃ , 1. 2, and pulverized coal, respectively. The reduc-tion and melting-separation reactions of the pellets contain direct reduction reaction, indirect reduction reaction, carbon gasification re-action, carburization reaction and iron melting reaction, and finally realize the separation of iron and slag.