西南石油大学学报(自然科学版)
西南石油大學學報(自然科學版)
서남석유대학학보(자연과학판)
JOURNAL OF SOUTHWEST PETROLEUM UNIVERSITY(SEIENCE & TECHNOLOGY EDITION)
2014年
5期
141-147
,共7页
齐自远%王业飞%王涛%王桂杰%于维钊
齊自遠%王業飛%王濤%王桂傑%于維釗
제자원%왕업비%왕도%왕계걸%우유쇠
阳离子聚合物%相对渗透率调节剂%静态吸附%润湿%选择性堵水
暘離子聚閤物%相對滲透率調節劑%靜態吸附%潤濕%選擇性堵水
양리자취합물%상대삼투솔조절제%정태흡부%윤습%선택성도수
cationic polymer%relative permeability modifier%static adsorption%wettability%selective water control
针对一种阳离子聚合物型相对渗透率调节剂,研究了RPM在不同润湿性砂子上的静态吸附以及选择性堵水性能。实验结果表明:RPM在油砂和石英砂上均发生单层吸附,且石英砂上的静态吸附量(1110μg/g)是其在油砂上的吸附量的2倍以上;吸附剂表面润湿性和聚合物链节的带电性是影响吸附量的两个重要因素;RPM的吸附可以使油湿石英表面(105°)转变为弱水湿(72°);采用了岩芯驱替实验研究RPM的选择性堵水能力:油、水相残余阻力系数随着渗透率、温度以及矿化度的增加而下降,聚合物吸附层的膨胀/收缩是RPM选择性堵水的合理解释。
針對一種暘離子聚閤物型相對滲透率調節劑,研究瞭RPM在不同潤濕性砂子上的靜態吸附以及選擇性堵水性能。實驗結果錶明:RPM在油砂和石英砂上均髮生單層吸附,且石英砂上的靜態吸附量(1110μg/g)是其在油砂上的吸附量的2倍以上;吸附劑錶麵潤濕性和聚閤物鏈節的帶電性是影響吸附量的兩箇重要因素;RPM的吸附可以使油濕石英錶麵(105°)轉變為弱水濕(72°);採用瞭巖芯驅替實驗研究RPM的選擇性堵水能力:油、水相殘餘阻力繫數隨著滲透率、溫度以及礦化度的增加而下降,聚閤物吸附層的膨脹/收縮是RPM選擇性堵水的閤理解釋。
침대일충양리자취합물형상대삼투솔조절제,연구료RPM재불동윤습성사자상적정태흡부이급선택성도수성능。실험결과표명:RPM재유사화석영사상균발생단층흡부,차석영사상적정태흡부량(1110μg/g)시기재유사상적흡부량적2배이상;흡부제표면윤습성화취합물련절적대전성시영향흡부량적량개중요인소;RPM적흡부가이사유습석영표면(105°)전변위약수습(72°);채용료암심구체실험연구RPM적선택성도수능력:유、수상잔여조력계수수착삼투솔、온도이급광화도적증가이하강,취합물흡부층적팽창/수축시RPM선택성도수적합리해석。
The static adsorption and selective water shutoff performance of a cationic polymer type relative permeability modi-fier(RPM)were studied. The results show that the static adsorptions of RPM on quartz sands and oil sands are both langmuir adsorption,and the adsorption on quartz sands is twice of that on oil sands;the static adsorption is strongly affected by electro-static attraction and the wettability of solid surface,and RPM can alter the oil wet surface(105°)to weakly water wet(72°);core flood tests are conducted to study the selective water shutoff of RPM,and it shows that the oil and water residual resis-tance factors decreases with the increase of permeability,temperature and brine salinity. The swelling/shrinking of polymer adsorption layer is a reasonable explanation for RPM selective water control.