陕西科技大学学报(自然科学版)
陝西科技大學學報(自然科學版)
협서과기대학학보(자연과학판)
JOURNAL OF SHAANXI UNIVERSITY OF SCIENCE & TECHNOLOGY
2014年
5期
63-67
,共5页
张光华%贾宇荣%李俊国%葛磊%李元博
張光華%賈宇榮%李俊國%葛磊%李元博
장광화%가우영%리준국%갈뢰%리원박
水煤浆%分散剂%缩聚物%腐植酸
水煤漿%分散劑%縮聚物%腐植痠
수매장%분산제%축취물%부식산
coal water slurry%dispersant%condensates%humic acid
以腐植酸为起始原料,采用先磺化、再与甲醛及磺化丙酮进行缩聚反应,合成了一种新型缩合型腐植酸水煤浆分散剂.通过红外光谱(IR)、热重(TGA)对其结构进行了表征,对分散剂应用于彬长煤制备水煤浆的性能进行了研究,并考察了目标产物水溶液对煤粒表面的动态接触角、与煤粒复合体系的Zeta电位、水煤浆的流变性能和稳定性等的影响.结果表明,该腐植酸水煤浆分散剂用量为0.3%(对干基煤质量),且获得的水煤浆浓度为67%时,其表观黏度为930 m Pa · s左右,且水煤浆的流变性和稳定性等性能较理想.
以腐植痠為起始原料,採用先磺化、再與甲醛及磺化丙酮進行縮聚反應,閤成瞭一種新型縮閤型腐植痠水煤漿分散劑.通過紅外光譜(IR)、熱重(TGA)對其結構進行瞭錶徵,對分散劑應用于彬長煤製備水煤漿的性能進行瞭研究,併攷察瞭目標產物水溶液對煤粒錶麵的動態接觸角、與煤粒複閤體繫的Zeta電位、水煤漿的流變性能和穩定性等的影響.結果錶明,該腐植痠水煤漿分散劑用量為0.3%(對榦基煤質量),且穫得的水煤漿濃度為67%時,其錶觀黏度為930 m Pa · s左右,且水煤漿的流變性和穩定性等性能較理想.
이부식산위기시원료,채용선광화、재여갑철급광화병동진행축취반응,합성료일충신형축합형부식산수매장분산제.통과홍외광보(IR)、열중(TGA)대기결구진행료표정,대분산제응용우빈장매제비수매장적성능진행료연구,병고찰료목표산물수용액대매립표면적동태접촉각、여매립복합체계적Zeta전위、수매장적류변성능화은정성등적영향.결과표명,해부식산수매장분산제용량위0.3%(대간기매질량),차획득적수매장농도위67%시,기표관점도위930 m Pa · s좌우,차수매장적류변성화은정성등성능교이상.
A novel humic acid based dispersant has been got from humic acid as basic raw ma-terials by sulfonation and condensation polymerization reaction .The copolymer was charac-terized and analyzed by infrared spectrum (IR) ,TGA .The contact angle of solution of dis-persant on coal particle surface and the Zeta potential of complex of dispersant and coal parti-cle has been made .The effects of the dosage of dispersant on apparent viscosity ,rheological behavior and static stability of coal water slurry have been investigated .The result have been showed when the dosage of dispersant is 0 .3% (based dry coal )the apparent viscosity of coal water slurry would be 930 mPa · s with the concentration of CWS was 67% .The perform-ance of rheological behavior and static stability of coal water slurry was meet demand .