工程塑料应用
工程塑料應用
공정소료응용
ENGINEERING PLASTICS APPLICATION
2014年
9期
37-41
,共5页
聚乳酸纤维%明胶%戊二醛%性能
聚乳痠纖維%明膠%戊二醛%性能
취유산섬유%명효%무이철%성능
PLA fiber%gelatin%glutaraldehyde%property
用己二胺和戊二醛处理聚乳酸(PLA)纤维,在纤维表面引入醛基,接枝明胶后获得表面亲水改性的PLA纤维。接枝明胶在改善纤维亲水性的同时保持了纤维的拉伸强度,还提高了纤维在碱性溶液中的湿热稳定性。经戊二醛交联,PLA纤维表面亲水性降低,水分难与纤维表面接触,热碱溶液处理后纤维力学损伤程度降低,进一步提高了PLA纤维的湿热稳定性。
用己二胺和戊二醛處理聚乳痠(PLA)纖維,在纖維錶麵引入醛基,接枝明膠後穫得錶麵親水改性的PLA纖維。接枝明膠在改善纖維親水性的同時保持瞭纖維的拉伸彊度,還提高瞭纖維在堿性溶液中的濕熱穩定性。經戊二醛交聯,PLA纖維錶麵親水性降低,水分難與纖維錶麵接觸,熱堿溶液處理後纖維力學損傷程度降低,進一步提高瞭PLA纖維的濕熱穩定性。
용기이알화무이철처리취유산(PLA)섬유,재섬유표면인입철기,접지명효후획득표면친수개성적PLA섬유。접지명효재개선섬유친수성적동시보지료섬유적랍신강도,환제고료섬유재감성용액중적습열은정성。경무이철교련,PLA섬유표면친수성강저,수분난여섬유표면접촉,열감용액처리후섬유역학손상정도강저,진일보제고료PLA섬유적습열은정성。
The hydrophilic modification of PLA fiber was conducted by surface grafting of gelatin onto the fibers. After treatment with hexanediamine and glutaraldehyde,the aldehyde groups which could react with gelatin were successfully introduced on the surface of PLA fiber. Modified with gelatin,the fiber exhibits good surface hydrophilic property while maintaining the tensile properties. In addition,its hydrothermal stability in alkali solutions is improved. Gelatin which is crosslinked with glutaraldehyde covers PLA fiber and prevents the fiber from contacting with water. As a result,the damage degree of tensile strength of the fiber decreased,indicating a higher hydrothermal stability.