CAJ | 학술논문

研究应用氢化物发生-微波等离子体原子发射光谱法同时测定印刷品中的砷（ As）、钡（ Ba）、汞（ Hg）、镉（ Cd）、铬（ Cr）、铅（ Pb）、锑（ Sb）、硒（ Se）8种有害可迁移元素。文中对比了多模式进样氢化物发生法与单通道进样模式的方法检出限，并进行了重复性、加标回收率实验。方法检出限对比实验结果表明，多模式进样氢化物发生法的方法检出限范围为0.0007～0.0198μg/mL，优于仪器检出限范围0.0002～0.2308μg/mL；重复性实验结果表明，各元素检测相对标准偏差小于1.8％；加标回收率范围为92.0％～120.0％。综上所述，该方法具有较好的精密度和准确性，适合印刷品中有害可迁移元素的分析。
연구응용경화물발생-미파등리자체원자발사광보법동시측정인쇄품중적신（ As）、패（ Ba）、홍（ Hg）、력（ Cd）、락（ Cr）、연（ Pb）、제（ Sb）、서（ Se）8충유해가천이원소。문중대비료다모식진양경화물발생법여단통도진양모식적방법검출한，병진행료중복성、가표회수솔실험。방법검출한대비실험결과표명，다모식진양경화물발생법적방법검출한범위위0.0007～0.0198μg/mL，우우의기검출한범위0.0002～0.2308μg/mL；중복성실험결과표명，각원소검측상대표준편차소우1.8％；가표회수솔범위위92.0％～120.0％。종상소술，해방법구유교호적정밀도화준학성，괄합인쇄품중유해가천이원소적분석。
The application of Hydride-microwave Plasma Atomic Emission Spectrometry ( MP-AES) to determine eight harmful migration elements , such as arsenic ( As ) , barium ( Ba ) , mercury ( Hg ) , cadmium ( Cd ) , chromium (Cr), lead (Pb), antimony (Sb), selenium (Se) in print at the same time was studied.The contrast experiment of method detection limit between the multimodal injection hydride method and the single channel sampling method , and repeatability experiments , the standard addition recovery rate experiments were carried out.The results of method detection limit experiments showed that the detection limit of multi -mode sample introduction system method was 0.000 7~0.019 8 μg/mL, which was better than the instrument detection limit which ranged from 0.000 2~0.230 8μg/mL.The results of repeatability experiments showed that the relative standard deviation was less than 1.8%of each element.The standard addition recovery rate of each element was in the range of 92.0% to 120.0%.The method was suitable for determination of the harmful migration elements in the print with its great simplicity and accuracy.