失效分析与预防
失效分析與預防
실효분석여예방
FAILURE ANALYSIS AND PREVENTION
2014年
5期
275-279
,共5页
李循迹%李厚补%常泽亮%戚东涛%毛学强%魏斌
李循跡%李厚補%常澤亮%慼東濤%毛學彊%魏斌
리순적%리후보%상택량%척동도%모학강%위빈
失效分析%固化度%玻璃化转变温度%塑料合金
失效分析%固化度%玻璃化轉變溫度%塑料閤金
실효분석%고화도%파리화전변온도%소료합금
failure analysis%state of cure%glass transition temperature%plastic alloy
集油管线用塑料合金复合管在使用过程中发生了管体爆裂失效事故。为了探讨复合管的失效原因,采用红外光谱分析、差热-热重分析、VST等分析手段,研究了复合管用内衬塑料层和外结构层玻璃钢树脂基体的结构成分、热性能等。结果表明:复合管内衬材料添加剂含量较多或分散不均,而复合管玻璃钢基体树脂的玻璃化转变温度远低于标准要求。较低的固化度和偏高的树脂含量导致玻璃钢结构层力学性能下降,在长期服役过程中的老化及介质腐蚀共同作用下,复合管最终爆裂失效。
集油管線用塑料閤金複閤管在使用過程中髮生瞭管體爆裂失效事故。為瞭探討複閤管的失效原因,採用紅外光譜分析、差熱-熱重分析、VST等分析手段,研究瞭複閤管用內襯塑料層和外結構層玻璃鋼樹脂基體的結構成分、熱性能等。結果錶明:複閤管內襯材料添加劑含量較多或分散不均,而複閤管玻璃鋼基體樹脂的玻璃化轉變溫度遠低于標準要求。較低的固化度和偏高的樹脂含量導緻玻璃鋼結構層力學性能下降,在長期服役過程中的老化及介質腐蝕共同作用下,複閤管最終爆裂失效。
집유관선용소료합금복합관재사용과정중발생료관체폭렬실효사고。위료탐토복합관적실효원인,채용홍외광보분석、차열-열중분석、VST등분석수단,연구료복합관용내츤소료층화외결구층파리강수지기체적결구성분、열성능등。결과표명:복합관내츤재료첨가제함량교다혹분산불균,이복합관파리강기체수지적파리화전변온도원저우표준요구。교저적고화도화편고적수지함량도치파리강결구층역학성능하강,재장기복역과정중적노화급개질부식공동작용하,복합관최종폭렬실효。
An anticorrosion plastic alloy composite pipe for oil gathering and transportation failed during service. Investigations were performed to identify the possible failure causes of the pipe. Composition and thermal analysis of inner plastic alloy and outer GRP resin were systematically studied by using FTIR, TG-DSC, VST, etc. Results reveal that additives in failed plastic alloy may have not been stirred enough before extrusion or the content of additives may exceed their normal range. The glass transition temperature of GRP resin was much lower than that stated in standard. Hence, the lower state of cure for resin as well as the higher resin content of GRP layer makes the outer GRP structural layer have a relatively lower mechanical property, giving rise to the final failure of the composite pipe after serving for a long time under the co-effect of the aging and corrosion.