南通职业大学学报
南通職業大學學報
남통직업대학학보
JOURNAL OF NANTONG VOCATIONAL COLLEGE
2014年
3期
89-91
,共3页
复合二元酸%环氧树脂%改性%预聚体
複閤二元痠%環氧樹脂%改性%預聚體
복합이원산%배양수지%개성%예취체
dibasic acid%epoxy resin%modified%prepolymer
用C36二聚酸、癸二酸与1,4-丁二醇二缩水甘油醚和双酚A型环氧树脂进行扩链反应,制备柔韧性环氧树脂预聚体。考察了配方组成、反应温度和催化剂等因素对羧基转化率的影响。结果表明,对于所给配方,当催化剂用量为0.1%,140℃下反应2 h,反应基本完全。另外,以柔韧性环氧树脂预聚体为基体树脂制备的固化物拉伸强度达到12.0 MPa,断裂伸长率为85%。
用C36二聚痠、癸二痠與1,4-丁二醇二縮水甘油醚和雙酚A型環氧樹脂進行擴鏈反應,製備柔韌性環氧樹脂預聚體。攷察瞭配方組成、反應溫度和催化劑等因素對羧基轉化率的影響。結果錶明,對于所給配方,噹催化劑用量為0.1%,140℃下反應2 h,反應基本完全。另外,以柔韌性環氧樹脂預聚體為基體樹脂製備的固化物拉伸彊度達到12.0 MPa,斷裂伸長率為85%。
용C36이취산、계이산여1,4-정이순이축수감유미화쌍분A형배양수지진행확련반응,제비유인성배양수지예취체。고찰료배방조성、반응온도화최화제등인소대최기전화솔적영향。결과표명,대우소급배방,당최화제용량위0.1%,140℃하반응2 h,반응기본완전。령외,이유인성배양수지예취체위기체수지제비적고화물랍신강도체도12.0 MPa,단렬신장솔위85%。
We process extender chain reaction with C36 dimer acid, sebacic acid, 1,4-butanediol diglycidyl and bisphenol A type epoxy resin, and produce flexible epoxy resin prepolymers. We investigate the influence of carboxyl conversion rate from formula composition, reaction temperature and catalyst and other factors. The results show that, for given formula, when the dosage of catalyst is 0.1%,it reacts 2h under 140 ℃, and the re-action is substantially complete. In addition, the flexibility of a cured epoxy resin prepolymer matrix resin composition prepared by a tensile strength of 12.0 MPa, elongation at break of 85%.