武汉科技大学学报(自然科学版)
武漢科技大學學報(自然科學版)
무한과기대학학보(자연과학판)
JOURNAL OF WUHAN UNIVERSITY OF SCIENCE AND TECHNOLOGY(NATURAL SCIENCE EDITION)
2014年
5期
379-381,390
,共4页
刘玉莉%秦义%廖锐全%陈超%鲁文婷
劉玉莉%秦義%廖銳全%陳超%魯文婷
류옥리%진의%료예전%진초%로문정
HPAM%弱凝胶%复合交联%耐温抗盐%性能评价
HPAM%弱凝膠%複閤交聯%耐溫抗鹽%性能評價
HPAM%약응효%복합교련%내온항염%성능평개
HPAM%weak gel%compound crosslinking%heat tolerance and salt resistance%performance evaluation
研制以聚丙烯酰胺(HPAM )为主剂、酚醛复合物和有机金属络合物为交联剂的耐温抗盐型复合交联弱凝胶体系,并与单一交联弱凝胶体系进行性能比较。结果表明,耐温抗盐型复合交联弱凝胶体系的优选配方为:HPAM、氯化铵、酚醛复合交联剂、有机金属络合物交联剂的质量浓度分别为1000、3000、300、25 mg/L ;与单一交联弱凝胶体系相比,复合交联弱凝胶体系在相同矿化度盐水中成胶,其黏度是单一交联弱凝胶体系黏度的8~10倍,在相同的温度下其黏度是单一交联弱凝胶体系黏度的3~4倍,在75℃下老化120 d ,其黏度依旧能保持在初始黏度的80%以上,具有优良的耐温、抗盐性能和良好的长期稳定性。
研製以聚丙烯酰胺(HPAM )為主劑、酚醛複閤物和有機金屬絡閤物為交聯劑的耐溫抗鹽型複閤交聯弱凝膠體繫,併與單一交聯弱凝膠體繫進行性能比較。結果錶明,耐溫抗鹽型複閤交聯弱凝膠體繫的優選配方為:HPAM、氯化銨、酚醛複閤交聯劑、有機金屬絡閤物交聯劑的質量濃度分彆為1000、3000、300、25 mg/L ;與單一交聯弱凝膠體繫相比,複閤交聯弱凝膠體繫在相同礦化度鹽水中成膠,其黏度是單一交聯弱凝膠體繫黏度的8~10倍,在相同的溫度下其黏度是單一交聯弱凝膠體繫黏度的3~4倍,在75℃下老化120 d ,其黏度依舊能保持在初始黏度的80%以上,具有優良的耐溫、抗鹽性能和良好的長期穩定性。
연제이취병희선알(HPAM )위주제、분철복합물화유궤금속락합물위교련제적내온항염형복합교련약응효체계,병여단일교련약응효체계진행성능비교。결과표명,내온항염형복합교련약응효체계적우선배방위:HPAM、록화안、분철복합교련제、유궤금속락합물교련제적질량농도분별위1000、3000、300、25 mg/L ;여단일교련약응효체계상비,복합교련약응효체계재상동광화도염수중성효,기점도시단일교련약응효체계점도적8~10배,재상동적온도하기점도시단일교련약응효체계점도적3~4배,재75℃하노화120 d ,기점도의구능보지재초시점도적80%이상,구유우량적내온、항염성능화량호적장기은정성。
With HPAM as the main agent and phenolic compounds and organometallic complex as crosslinking agents ,heat-tolerant and salt-resistant compound crosslinking weak gel system was de-veloped .The results show that the best formula for the preparation of compound crosslinking weak gel system is HPAM at 1000 mg/L ,chloride at 3000 mg/L ,phenolic compound at 300 mg/L ,and an organic metal compound crosslinking agent at 25 mg/L .Compared with the single crosslinking weak gel system ,the compound crosslinking system boasts a viscosity 8 to 10 times that of the former un-der the same condition of salinity . Under the same temperature , the viscosity of the compound crosslinking system is 3 to 4 times that of the single crosslinking system .Placed at 75 ℃ for 120 days ,the compound crosslinking system’s viscosity is still 80% of its initial viscosity ,w hich indicates that the compound crosslinking system has excellent heat tolerance ,salt resistance and good long-term stability .