CAJ | 학술논문

采用H3 PO4，Al（ OH）3为主要原料合成金属基陶瓷涂层用无机胶粘剂，以磷酸盐胶粘剂为基料，添加氧化铜为固化剂，通过设计氧化铜和磷酸盐的配比即调胶比配制而成；并将其刷涂在金属基体表面。研究氧化铜粒度、调胶比、固化温度和时间对胶黏剂粘结强度的影响；利用电子万能试验机测试其拉伸、剪切强度。采用扫描电镜分析粘结机理。结果表明：随着磷酸盐密度增大，调胶比由小到大时，胶粘剂的粘接强度由大变小。随着固化时间的增加，胶粘剂的粘接强度增大；随着固化温度的升高，胶粘剂的粘接强度先增大后减小。胶粘剂Al／P＝1：3、氧化铜粉粒径为200～400目、调胶比为4g／ml、固化温度为160℃、固化时间不少于3h时，能达到理想的粘接强度。基体与胶粘剂的界面结合强度源于机械互锁与互扩散。
채용H3 PO4，Al（ OH）3위주요원료합성금속기도자도층용무궤효점제，이린산염효점제위기료，첨가양화동위고화제，통과설계양화동화린산염적배비즉조효비배제이성；병장기쇄도재금속기체표면。연구양화동립도、조효비、고화온도화시간대효점제점결강도적영향；이용전자만능시험궤측시기랍신、전절강도。채용소묘전경분석점결궤리。결과표명：수착린산염밀도증대，조효비유소도대시，효점제적점접강도유대변소。수착고화시간적증가，효점제적점접강도증대；수착고화온도적승고，효점제적점접강도선증대후감소。효점제Al／P＝1：3、양화동분립경위200～400목、조효비위4g／ml、고화온도위160℃、고화시간불소우3h시，능체도이상적점접강도。기체여효점제적계면결합강도원우궤계호쇄여호확산。
The metal matrix ceramic inorganic adhesive was prepared by the reaction of Al ( OH ) 3 and H3 PO4 .The based material phosphate adhesive and curing agent copper oxide were coated on the surface of met -al substrate with different tune -cement ratio .The effect of copper oxide particle size , tune-cement ratio , cu-ring temperature and time was studied .The tensile shear strength was tested by electronic universal testing ma-chine .The bond mechanism was analyzed by scanning electron microscopy .The results showed that with the in-crease of density of phosphate and glue ratio , the bonding strength of adhesive decreased , with the increase of curing time, the bonding strength of adhesive increased , and with the increase of curing temperature , the bond-ing strength of adhesive increased firstly and then decreased .The desired bond strength was achieved in condi-tion of adhesive Al/P=1:3, copper oxide particle size of 200~400 meshes, glue ratio of 4g/ml, curing temper-ature of 160℃, and the curing time of not less than 3h.The substrate and adhesive was combined due to me-chanical interlocking and mutual diffusion .