昆明理工大学学报(自然科学版)
昆明理工大學學報(自然科學版)
곤명리공대학학보(자연과학판)
JOURNAL OF KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGY(SCIENCE AND TECHNOLOGY)
2014年
5期
11-15,25
,共6页
李法社%杜威%包桂蓉%王华%李明%苏成帅%杨梅
李法社%杜威%包桂蓉%王華%李明%囌成帥%楊梅
리법사%두위%포계용%왕화%리명%소성수%양매
生物柴油%低温流动性能%降凝剂%油酸异丙酯
生物柴油%低溫流動性能%降凝劑%油痠異丙酯
생물시유%저온류동성능%강응제%유산이병지
biodiesel%low temperature fluidity%pour point depressant%oleic acid isopropyl ester
以地沟油和橡胶籽油为原料,制备相应生物柴油,测定其物化性能指标,地沟油生物柴油与橡胶籽油生物柴油的凝点与冷滤点分别是3℃、-1℃和6℃、2℃,40℃时运动粘度分别为5.78 mm2/s和5.0 mm2/s,其低温流动性能较差,严重影响了生物柴油使用和发展.考察了降凝剂I和降凝剂II对地沟油生物柴油与橡胶籽油生物柴油的低温流动性能,采用与低温流动特性较好的0#柴油调合混配可改进生物柴油低温流动特性,使生物柴油的凝点、冷滤点和运动粘度都能很好地得到改进.添加带有支链的油酸异丙酯可以很好地改进生物柴油的低温性能,但会使生物柴油运动粘度升高,选取适当的调合比例可以很好地改进生物柴油的低温流动性能.
以地溝油和橡膠籽油為原料,製備相應生物柴油,測定其物化性能指標,地溝油生物柴油與橡膠籽油生物柴油的凝點與冷濾點分彆是3℃、-1℃和6℃、2℃,40℃時運動粘度分彆為5.78 mm2/s和5.0 mm2/s,其低溫流動性能較差,嚴重影響瞭生物柴油使用和髮展.攷察瞭降凝劑I和降凝劑II對地溝油生物柴油與橡膠籽油生物柴油的低溫流動性能,採用與低溫流動特性較好的0#柴油調閤混配可改進生物柴油低溫流動特性,使生物柴油的凝點、冷濾點和運動粘度都能很好地得到改進.添加帶有支鏈的油痠異丙酯可以很好地改進生物柴油的低溫性能,但會使生物柴油運動粘度升高,選取適噹的調閤比例可以很好地改進生物柴油的低溫流動性能.
이지구유화상효자유위원료,제비상응생물시유,측정기물화성능지표,지구유생물시유여상효자유생물시유적응점여랭려점분별시3℃、-1℃화6℃、2℃,40℃시운동점도분별위5.78 mm2/s화5.0 mm2/s,기저온류동성능교차,엄중영향료생물시유사용화발전.고찰료강응제I화강응제II대지구유생물시유여상효자유생물시유적저온류동성능,채용여저온류동특성교호적0#시유조합혼배가개진생물시유저온류동특성,사생물시유적응점、랭려점화운동점도도능흔호지득도개진.첨가대유지련적유산이병지가이흔호지개진생물시유적저온성능,단회사생물시유운동점도승고,선취괄당적조합비례가이흔호지개진생물시유적저온류동성능.
Ditch oil and rubber see d oil are used as raw material to prepare correspondingbiodiesel,whose physi-cal and chemical performance index are then measured.The solidifying point and cold filter plugging point of ditch oil biodiesel is 3℃and 6℃.The solidifying point and cold filter plugging point of rubber seed oil biodiesel is-1℃ and 2℃.The kinematic viscosity at 40℃ is 5.78mm2/s and 5.0mm2/s.Their poor low temperature fluidity seriously has significant negative influence on the usage and development of biodiesel.Based on the per-formance of pour point depressant I and pour point depressant II to the low temperature fluidity of ditch oil biodiesel and rubber seed oil biodiesel,the low temperature fluidity of biodiesel is improved when mixed with 0#diesel oil whose low temperature fluidity is better,making the solidifying point,cold filter plugging point and ki-nematic viscosity of biodiesel improve greatly.Blending oleic acid isopropyl ester with branched chain can im-prove the low temperature fluidity of biodiesel greatly while making kinematic viscosity of biodiesel rise.Choosing proper blending ratio can improve the low temperature fluidity of biodiesel effectively.