CAJ | 학술논문

为选择性降低卷烟主流烟气中氢氰酸（H C N）的释放量，采用水热合成法制备了金属有机骨架（MOFs）多孔材料均苯三甲酸合铜（Ⅱ）（Cu-BTC），运用X射线粉末衍射（XPRD）、比表面积孔径分析（B E T）、热重分析（T G）等技术对材料的晶体结构、孔结构参数及热稳定性进行了表征，并将材料添加于卷烟滤嘴中进行了烟气减害测试。结果表明：①Cu-BTC是一种典型的MOFs多孔材料，在270℃以下具有良好的热稳定性。②在卷烟添加剂减害性能模拟评价条件下，Cu-BTC对卷烟主流烟气中HCN的降低效果可达51.9%；在卷烟应用试验中，Cu-BTC对卷烟主流烟气中HCN的选择性降低率为21.83%，而常规烟气成分释放量与对照卷烟基本一致。
위선택성강저권연주류연기중경청산（H C N）적석방량，채용수열합성법제비료금속유궤골가（MOFs）다공재료균분삼갑산합동（Ⅱ）（Cu-BTC），운용X사선분말연사（XPRD）、비표면적공경분석（B E T）、열중분석（T G）등기술대재료적정체결구、공결구삼수급열은정성진행료표정，병장재료첨가우권연려취중진행료연기감해측시。결과표명：①Cu-BTC시일충전형적MOFs다공재료，재270℃이하구유량호적열은정성。②재권연첨가제감해성능모의평개조건하，Cu-BTC대권연주류연기중HCN적강저효과가체51.9%；재권연응용시험중，Cu-BTC대권연주류연기중HCN적선택성강저솔위21.83%，이상규연기성분석방량여대조권연기본일치。
To selectively reduce the delivery of hydrocyanic acid (HCN) in mainstream cigarette smoke, a porous material with metal-organic framework (MOF), copper-1, 3, 5-benzenetricarboxylic acid (Ⅱ) (Cu-BTC), was prepared by hydrothermal synthesis method. The crystal structure, pore structure and thermal stability of the prepared material were characterized by X-Ray powder diffraction, BET surface area analysis and thermal gravimetric analysis. The material was added into cigarette filter to test its harm reducing effect. The results showed that: 1) Cu-BTC was a typical MOF porous material with excellent thermal stability under 270 ℃. 2) Under the conditions of a simulated device for evaluating the harm reducing effects of cigarette additives, the reduction rate of HCN in mainstream cigarette smoke by Cu-BTC reached 51.9%; in a real cigarette experiment, the selective reduction rate of HCN by Cu-BTC was 21.83%, while the deliveries of routine components in cigarette smoke were basically similar to the control.