化学工程师
化學工程師
화학공정사
CHEMICAL ENGINEER
2014年
10期
30-33
,共4页
顾平%吴德东%周爱申%马玉坤
顧平%吳德東%週愛申%馬玉坤
고평%오덕동%주애신%마옥곤
二氧化硫%大气%颗粒物%稳定性%哈尔滨
二氧化硫%大氣%顆粒物%穩定性%哈爾濱
이양화류%대기%과립물%은정성%합이빈
sulfur dioxide(SO2)%atmospheric%particles%stability%Harbin
针对东北地区煤炭燃烧引起的颗粒物和SO2污染问题,采用甲醛吸收-副玫瑰苯胺分光光度法,通过对比TSP和IP样品中SO2的含量,考察时间和温湿度与SO2含量的关系。结果表明,哈尔滨市冬季大气颗粒物中SO2转化缓慢,较为稳定,但温湿度的增加有利于颗粒物中的SO2的转化,在IP和TSP中的SO2体积浓度和质量分数存在一定的差异,但总体变化趋势是一致的。大气颗粒物中S (IV)主要以SO2和HOCH2SO3H两种形式存在。
針對東北地區煤炭燃燒引起的顆粒物和SO2汙染問題,採用甲醛吸收-副玫瑰苯胺分光光度法,通過對比TSP和IP樣品中SO2的含量,攷察時間和溫濕度與SO2含量的關繫。結果錶明,哈爾濱市鼕季大氣顆粒物中SO2轉化緩慢,較為穩定,但溫濕度的增加有利于顆粒物中的SO2的轉化,在IP和TSP中的SO2體積濃度和質量分數存在一定的差異,但總體變化趨勢是一緻的。大氣顆粒物中S (IV)主要以SO2和HOCH2SO3H兩種形式存在。
침대동북지구매탄연소인기적과립물화SO2오염문제,채용갑철흡수-부매괴분알분광광도법,통과대비TSP화IP양품중SO2적함량,고찰시간화온습도여SO2함량적관계。결과표명,합이빈시동계대기과립물중SO2전화완만,교위은정,단온습도적증가유리우과립물중적SO2적전화,재IP화TSP중적SO2체적농도화질량분수존재일정적차이,단총체변화추세시일치적。대기과립물중S (IV)주요이SO2화HOCH2SO3H량충형식존재。
For particulate matter and sulfur dioxide (SO2) pollution caused by coal burning in Northeast, the relationship between, temperature, humidity and SO2 content with time were investigated by comparing the SO2 content of TSP and IP samples, with formaldehyde absorption - pararosaniline spectrophotometry. The results showed that in winter SO2 conversion of atmospheric particulate matter was slow in Harbin, which was more stable, but the increase of temperature and humidity was conducive to SO 2 conversion of particulate matter., There were some differences in IP and TSP that the volume concentration and mass fraction of SO 2, but the overall change trend was consistent. In atmospheric particulate matter, S(IV) mainly exists in two forms of SO2 and HOCH2SO3H.