CAJ | 학술논문

对神华煤加氢液化残渣依次使用正庚烷、甲苯、吡啶进行萃取，分别得到正庚烷可溶物（HS）、正庚烷不溶-甲苯可溶物（HI-TS）以及甲苯不溶-吡啶可溶物（TI-PS）3种可溶组分。分别以HI-TS及TI-PS两种组分为原料，采用直接热缩聚法，制备了中间相沥青（MP）。通过偏光显微镜、凝胶渗透色谱（GPC）等仪器分析手段对合成的中间相沥青进行了形貌及组成表征。实验结果表明：HI-TS组分在反应温度380℃，反应时间为6 h，TI-PS组分在反应温度380℃，反应时间4 h，均生成了光学组织结构好、中间相含量近100%的中间相沥青。
대신화매가경액화잔사의차사용정경완、갑분、필정진행췌취，분별득도정경완가용물（HS）、정경완불용-갑분가용물（HI-TS）이급갑분불용-필정가용물（TI-PS）3충가용조분。분별이HI-TS급TI-PS량충조분위원료，채용직접열축취법，제비료중간상력청（MP）。통과편광현미경、응효삼투색보（GPC）등의기분석수단대합성적중간상력청진행료형모급조성표정。실험결과표명：HI-TS조분재반응온도380℃，반응시간위6 h，TI-PS조분재반응온도380℃，반응시간4 h，균생성료광학조직결구호、중간상함량근100%적중간상력청。
Shenhua coal hydro-liquefaction residue was extracted by n-heptane (H), toluene (T) and pyridine (P), successively, and the soluble fractions including HS, HI-TS and TI-PS were obtained. Mesophase pitches using HI-TS and TI-PS as the precursors were prepared by the direct heat polycondensation, respectively. The structure and properties of MP were analyzed by means of po-larization microscope and GPC. It was found that both HI-TS and TI-PS can produce mesophase pitches with fine optical texture and 100%anisotropic content.