中国石油大学学报(自然科学版)
中國石油大學學報(自然科學版)
중국석유대학학보(자연과학판)
JOURNAL OF CHINA UNIVERSITY OF PETROLEUM(EDITION OF NATURAL SCIENCE)
2014年
5期
102-108
,共7页
煤层气%压裂液%孔隙结构%氮气吸附%等温吸附
煤層氣%壓裂液%孔隙結構%氮氣吸附%等溫吸附
매층기%압렬액%공극결구%담기흡부%등온흡부
coalbed methane%fracturing fluid%pore structure%nitrogen adsorption%isothermal adsorption
煤层气压裂作业中必然发生压裂液与煤层的相互接触,煤岩微裂隙发育和毛管压力高等特点导致压裂液极易侵入煤层对煤岩孔隙结构造成严重损害,进而改变煤岩对煤层气的吸附能力。选取宁武盆地9号煤和现场用压裂液,采用氮气吸附和扫描电镜( SEM)表征压裂液处理前后煤样孔隙结构,探求不同体系压裂液处理对煤岩孔隙结构的影响,开展压裂液处理前后煤样的等温吸附实验。结果表明:压裂液处理后煤样孔径分布、比表面积及孔隙分形维数都将发生变化;压裂液体系对煤样孔隙结构的影响程度为瓜胶压裂液>活性水压裂液>清洁压裂液;压裂液处理后煤样比表面积与孔隙分形维数增量越大,其对甲烷气体吸附能力越强,煤岩孔隙结构的变化会改变甲烷气体的吸附能力。
煤層氣壓裂作業中必然髮生壓裂液與煤層的相互接觸,煤巖微裂隙髮育和毛管壓力高等特點導緻壓裂液極易侵入煤層對煤巖孔隙結構造成嚴重損害,進而改變煤巖對煤層氣的吸附能力。選取寧武盆地9號煤和現場用壓裂液,採用氮氣吸附和掃描電鏡( SEM)錶徵壓裂液處理前後煤樣孔隙結構,探求不同體繫壓裂液處理對煤巖孔隙結構的影響,開展壓裂液處理前後煤樣的等溫吸附實驗。結果錶明:壓裂液處理後煤樣孔徑分佈、比錶麵積及孔隙分形維數都將髮生變化;壓裂液體繫對煤樣孔隙結構的影響程度為瓜膠壓裂液>活性水壓裂液>清潔壓裂液;壓裂液處理後煤樣比錶麵積與孔隙分形維數增量越大,其對甲烷氣體吸附能力越彊,煤巖孔隙結構的變化會改變甲烷氣體的吸附能力。
매층기압렬작업중필연발생압렬액여매층적상호접촉,매암미렬극발육화모관압력고등특점도치압렬액겁역침입매층대매암공극결구조성엄중손해,진이개변매암대매층기적흡부능력。선취저무분지9호매화현장용압렬액,채용담기흡부화소묘전경( SEM)표정압렬액처리전후매양공극결구,탐구불동체계압렬액처리대매암공극결구적영향,개전압렬액처리전후매양적등온흡부실험。결과표명:압렬액처리후매양공경분포、비표면적급공극분형유수도장발생변화;압렬액체계대매양공극결구적영향정도위과효압렬액>활성수압렬액>청길압렬액;압렬액처리후매양비표면적여공극분형유수증량월대,기대갑완기체흡부능력월강,매암공극결구적변화회개변갑완기체적흡부능력。
Fracturing fluid and the coal seam will touch each other during fracturing operation of coal. The developed micro-fractures and high capillary pressure of coal make it easy for fracturing fluid intrude into coal seam and therefore cause serious damage to the pore structure, which affects further the adsorption capacity of coal bed methane. Using the NO. 9 coal sample from Ningwu Basin and three fracturing fluid samples on site, the characterization of pore structure of coal, which was treated with fracturing fluid, was analyzed with nitrogen adsorption method. Combined with the analysis results of scanning electron mi-croscopy ( SEM) , the influence of different fracturing fluid on pore structure of coal was investigated. Methane isothermal ad-sorption experiments were also carried out using the treated coal. The results show that pore size distribution, specific surface area and pore fractal dimension of coal change after treated by fracturing fluid. The results also indicate that gel fracturing fluid has the most impact on pore structure of coal, followed by activated water fracturing fluid, and clean fracturing fluid having the least. The larger the increase of specific surface area and pore fractal dimension of coal treated by fracturing fluid, the stronger its ability of methane adsorption. Therefore, the change of pore structure in coal will change its adsorption ability of methane.