石油与天然气化工
石油與天然氣化工
석유여천연기화공
CHEMICAL ENGINEERING OF OIL AND GAS
2014年
5期
574-578
,共5页
邓骥%诸林%肖娅%赵启龙
鄧驥%諸林%肖婭%趙啟龍
산기%제림%초아%조계룡
含氧煤层气%液化%模拟%爆炸极限%惰化
含氧煤層氣%液化%模擬%爆炸極限%惰化
함양매층기%액화%모의%폭작겁한%타화
oxygen-bearing coal-bed methane%liquefaction%simulation%flammability limits%inerting
矿下抽采的煤层气由于混有空气而在液化中存在爆炸危险。通过将HYSYS对常规液化分离流程的模拟结果与爆炸极限理论相结合进行分析计算得出:爆炸危险主要集中在冷凝终了处和精馏塔顶部。进而提出降低压缩机出口压力或提高最终冷凝温度;严格控制精馏塔塔顶气相C H4含量在爆炸上限之上,塔顶气用N2惰化后再与液氮逆流接触以进一步回收C H4。计算表明,当N2注入比达0.6(摩尔比),气相CH4含量曲线将绕过临界点进入安全区。采取措施后CH4有较高收率且液化流程安全性得以提高。
礦下抽採的煤層氣由于混有空氣而在液化中存在爆炸危險。通過將HYSYS對常規液化分離流程的模擬結果與爆炸極限理論相結閤進行分析計算得齣:爆炸危險主要集中在冷凝終瞭處和精餾塔頂部。進而提齣降低壓縮機齣口壓力或提高最終冷凝溫度;嚴格控製精餾塔塔頂氣相C H4含量在爆炸上限之上,塔頂氣用N2惰化後再與液氮逆流接觸以進一步迴收C H4。計算錶明,噹N2註入比達0.6(摩爾比),氣相CH4含量麯線將繞過臨界點進入安全區。採取措施後CH4有較高收率且液化流程安全性得以提高。
광하추채적매층기유우혼유공기이재액화중존재폭작위험。통과장HYSYS대상규액화분리류정적모의결과여폭작겁한이론상결합진행분석계산득출:폭작위험주요집중재냉응종료처화정류탑정부。진이제출강저압축궤출구압력혹제고최종냉응온도;엄격공제정류탑탑정기상C H4함량재폭작상한지상,탑정기용N2타화후재여액담역류접촉이진일보회수C H4。계산표명,당N2주입비체0.6(마이비),기상CH4함량곡선장요과림계점진입안전구。채취조시후CH4유교고수솔차액화류정안전성득이제고。
There is a risk of explosion during purifying the coal-bed methane coming from un-derground drainage ,for the reason that the gas contains oxygen .In this paper ,the results of simulation with HYSYS and the flammability limit theory were combined together to analyze the security of whole process .The results showed that the explosion hazard concentrated at the end of the condensation and on the top of rectification tower .The measure to reduce the compressor outlet pressure or raise the final condensation temperature was proposed .What′s more ,the secu-rity measure was proposed to control the methane content of rectification tower gas above the up-per limit of the explosion strictly ,and then the inerting gas with nitrogen contacts with liquid ni-trogen upstream for further recovery of CH4 .The results indicate that when the value of nitrogen injection ratio is greater than 0 .6 (mole ratio ) ,there is no danger of explosion in liquefaction process ,and both methane yield and process safety are improved greatly in this way .