检验检疫学刊
檢驗檢疫學刊
검험검역학간
INSPECTION AND QUARANTINE SCIENCE
2014年
5期
18-20
,共3页
潘亚利%赵发宝%姚亚婷%康利华%刘海峰
潘亞利%趙髮寶%姚亞婷%康利華%劉海峰
반아리%조발보%요아정%강리화%류해봉
煤%微波消解%原子荧光光谱%砷
煤%微波消解%原子熒光光譜%砷
매%미파소해%원자형광광보%신
Coal%Microwave Digestion%Atomic Fluorescence Spectrometry%Arsenic
应用微波消解和原子荧光光谱法测定煤中砷。通过对微波消解和原子荧光光谱法的实验条件进行优化，确定了最佳实验条件。方法的线性范围为0.4-200 ng/mL，相关系数r为0.9994，方法检出限为0.12ng/mL，定量限为0.36ng/mL，方法回收率为94.87%-96.80%，RSD%≤3.20%。该方法操作简单、快速、灵敏度高，可用于煤样品中砷含量的测定。
應用微波消解和原子熒光光譜法測定煤中砷。通過對微波消解和原子熒光光譜法的實驗條件進行優化，確定瞭最佳實驗條件。方法的線性範圍為0.4-200 ng/mL，相關繫數r為0.9994，方法檢齣限為0.12ng/mL，定量限為0.36ng/mL，方法迴收率為94.87%-96.80%，RSD%≤3.20%。該方法操作簡單、快速、靈敏度高，可用于煤樣品中砷含量的測定。
응용미파소해화원자형광광보법측정매중신。통과대미파소해화원자형광광보법적실험조건진행우화，학정료최가실험조건。방법적선성범위위0.4-200 ng/mL，상관계수r위0.9994，방법검출한위0.12ng/mL，정량한위0.36ng/mL，방법회수솔위94.87%-96.80%，RSD%≤3.20%。해방법조작간단、쾌속、령민도고，가용우매양품중신함량적측정。
Method for determination of arsenic in coal by Microwave Digestion-Atomic Fluorescence Spectrometry was established. The influences of instrument parameters on the determination of arsenic were studied. The analytical conditions were optimized. The linear range was 0.4-200 ng/L and the correlation coefficient, 0.9994. The detection limits was 0.12 ng/mL, and the recovery, 94.87%-96.80% and the relative standard deviation, ≤3.20% respectively. The method was simple, rapid, sensitive and can be applied in the determination of arsenic in coal.
