CAJ | 학술논문

为分析复合粘结剂的组成和配比对高聚物粘结炸药（PBX）界面作用的影响，基于不同理论模型，采用多个参数（参数 A、β和有效体积分数φ e ）评估了氟树脂 F2314/丙烯腈-苯乙烯共聚物（ AS）复合材料与1，3，5-三氨基-2，4，6-三硝基苯（ TATB）的界面作用。结果表明，F2314/AS 复合粘结剂与 TATB 的界面作用与 F2314和 AS 的相转变有关，随着温度升高呈现较大波动。TATB /F2314和 TATB /AS 复合材料的界面作用参数β值分别为0．969和0．840。20℃时炸药颗粒的有效体积分数φ e 和单个颗粒有效体积的相对值 B 随 F2314含量增加而增加。随着 F2314含量增加，PBX 中 TATB 炸药颗粒和粘结剂的界面作用增强。
위분석복합점결제적조성화배비대고취물점결작약（PBX）계면작용적영향，기우불동이론모형，채용다개삼수（삼수 A、β화유효체적분수φ e ）평고료불수지 F2314/병희정-분을희공취물（ AS）복합재료여1，3，5-삼안기-2，4，6-삼초기분（ TATB）적계면작용。결과표명，F2314/AS 복합점결제여 TATB 적계면작용여 F2314화 AS 적상전변유관，수착온도승고정현교대파동。TATB /F2314화 TATB /AS 복합재료적계면작용삼수β치분별위0．969화0．840。20℃시작약과립적유효체적분수φ e 화단개과립유효체적적상대치 B 수 F2314함량증가이증가。수착 F2314함량증가，PBX 중 TATB 작약과립화점결제적계면작용증강。
To analyze the effects of component and proportion of composite binder on the interfacial interaction of polymer bonded explosive(PBX),based on different theoretical models,the interfacial interaction between fluoropolymer F2314 /acrylonitrile-styrene copolymer(AS)composite and 1,3,5-triamino-2,4,6-trinitrobenzene( TATB)was evaluated using multiple parameters (parameters A、β and effective volume fraction φ e ). Results show that the interfacial interaction between F2314 /AS composite binder and TATB is related to phase transition of F2314 and AS,with a fluctuation as temperature increases. The values of interfa-cial interaction parameter β of TATB /F2314 composite and TATB /AS composite are 0. 969 and 0. 840,respectively. With the F2314 content increasing at 20 ℃,the effective volume fraction φ e of explosive particles and the relative value of the effective volume per single particle B increase,and the interfacial interaction between explosive particles and composite binders in PBX can be enhanced.