中国环境科学
中國環境科學
중국배경과학
CHINA ENVIRONMENTAL SCIENCE
2014年
10期
2513-2521
,共9页
邱松凯%范举红%黄开坚%陈新芳%陈泽枝%晓刚%刘锐%陈建孟%陈吕军
邱鬆凱%範舉紅%黃開堅%陳新芳%陳澤枝%曉剛%劉銳%陳建孟%陳呂軍
구송개%범거홍%황개견%진신방%진택지%효강%류예%진건맹%진려군
垃圾焚烧渗滤液%深度处理%臭氧氧化%曝气生物滤池
垃圾焚燒滲濾液%深度處理%臭氧氧化%曝氣生物濾池
랄급분소삼려액%심도처리%취양양화%폭기생물려지
leachate from municipal solid wastes incineration plant%advanced treatment%ozonation%BAF
研究了臭氧-曝气生物滤池(BAF)代替纳滤和反渗透深度处理垃圾焚烧渗滤液达标排放的技术可行性.半间歇臭氧氧化试验表明,实验用水的可生化性随着氧化时间的增加而增加,色度及UV254,15min内去除率分别达91%和64%;氧化时间为45min时COD去除率59%,45min后COD去除较慢,120min时去除率77%.确定臭氧氧化时间为1h,在同样臭氧浓度与流量下进行了臭氧-BAF处理垃圾焚烧渗滤液的连续实验.结果发现,此工艺对COD、色度和UV254的去除率分别可达75%,95%和90%,其中2/3运行时间里COD低于排放标准100 mg/L.其中出水色度可稳定保持在40度以下达标排放.经过进一步优化,臭氧-BAF有望用于垃圾焚烧渗滤液的达标处理.GC-MS检测表明烷烃,芳香族化合物及含氮杂环化合物是试验用水的主要污染物,臭氧-BAF能够有效去除后两类化合物,但难以去除烷烃.
研究瞭臭氧-曝氣生物濾池(BAF)代替納濾和反滲透深度處理垃圾焚燒滲濾液達標排放的技術可行性.半間歇臭氧氧化試驗錶明,實驗用水的可生化性隨著氧化時間的增加而增加,色度及UV254,15min內去除率分彆達91%和64%;氧化時間為45min時COD去除率59%,45min後COD去除較慢,120min時去除率77%.確定臭氧氧化時間為1h,在同樣臭氧濃度與流量下進行瞭臭氧-BAF處理垃圾焚燒滲濾液的連續實驗.結果髮現,此工藝對COD、色度和UV254的去除率分彆可達75%,95%和90%,其中2/3運行時間裏COD低于排放標準100 mg/L.其中齣水色度可穩定保持在40度以下達標排放.經過進一步優化,臭氧-BAF有望用于垃圾焚燒滲濾液的達標處理.GC-MS檢測錶明烷烴,芳香族化閤物及含氮雜環化閤物是試驗用水的主要汙染物,臭氧-BAF能夠有效去除後兩類化閤物,但難以去除烷烴.
연구료취양-폭기생물려지(BAF)대체납려화반삼투심도처리랄급분소삼려액체표배방적기술가행성.반간헐취양양화시험표명,실험용수적가생화성수착양화시간적증가이증가,색도급UV254,15min내거제솔분별체91%화64%;양화시간위45min시COD거제솔59%,45min후COD거제교만,120min시거제솔77%.학정취양양화시간위1h,재동양취양농도여류량하진행료취양-BAF처리랄급분소삼려액적련속실험.결과발현,차공예대COD、색도화UV254적거제솔분별가체75%,95%화90%,기중2/3운행시간리COD저우배방표준100 mg/L.기중출수색도가은정보지재40도이하체표배방.경과진일보우화,취양-BAF유망용우랄급분소삼려액적체표처리.GC-MS검측표명완경,방향족화합물급함담잡배화합물시시험용수적주요오염물,취양-BAF능구유효거제후량류화합물,단난이거제완경.
This study attempted to substitute the nanofiltration (NF)- reverse osmosis (RO) process with ozonation-biological aerated filter (BAF) in the advanced treatment of leachate from municipal solid wastes incineration plant. Semi-batch ozonation test in a 10 L column reactor demonstrated that the biodegradability of test leachate improved as ozonation time increased, 91%of color and 64%of UV254 could be removed within 15 min, the COD removal rate was 59% within the first 45 min, but thereafter slowed down with a removal rate of 77% at 120 min. Continuous flow test revealed that 1 h of ozonation (78.8 mg/L, 3.7 mL/min) followed with BAF (HRT=4.3h) could remove 75%of COD, 95%of color and 89%of UV254 from the leachate. The effluent COD remained below the discharge standard during 2/3 of the operational time and the effluent color was able to meet the discharge standard. The above results suggested the possibilities of substituting NF-RO with ozonation-BAF to treat waste leachate. The results of GC-MS indicated that the dominant pollutants in the test water were alkanes, aromatic compounds and heterocyclic compounds containing nitrogen, and ozonation-BAF was effective in removing the later two kinds of pollutants, but difficult in removing alkanes.