合肥工业大学学报(自然科学版)
閤肥工業大學學報(自然科學版)
합비공업대학학보(자연과학판)
JOURNAL OF HEFEI UNIVERSITY OF TECHNOLOGY(NATURAL SCIENCE)
2014年
10期
1168-1172,1225
,共6页
程建萍%孙秋阳%胡淑恒%陈少华%汪家权
程建萍%孫鞦暘%鬍淑恆%陳少華%汪傢權
정건평%손추양%호숙항%진소화%왕가권
微生物燃料电池%硝酸盐%生物阴极%电子传递%菌群
微生物燃料電池%硝痠鹽%生物陰極%電子傳遞%菌群
미생물연료전지%초산염%생물음겁%전자전체%균군
microbial fuel cell(M FC)%nitrate%biocathode%electron transferring%flora
文章以硝酸盐溶液为阴极的电子受体,在阴极室中分别接种活性污泥混合菌和纯反硝化单菌株,构成生物阴极微生物燃料电池(microbial fuel cell ,简称MFC)A-MFC和B-MFC。实验结果表明:在外接电阻为100Ω情况下,A-MFC和B-M FC最大输出电压分别为119.6 mV和117.2 mV ,硝酸盐在B-M FC阴极室的平均反硝化速率为2.19 mg/(L·d),比A-MFC中的平均反硝化速率1.86 mg/(L·d)略高;扫描电镜观察到A-MFC和B-M FC的阴极碳布纤维丝表面形貌存在差异,A-MFC中碳布被孔状结构物覆盖,而B-M FC阴极碳布被片层状结构物所覆盖;同时发现A-MFC的阴极碳布循环伏安法CV曲线上均出现了明显的还原峰,表明A-MFC阴极碳布上的微生物进行了催化还原反应,而且阴极溶液均出现1对明显的氧化还原电对,说明阴极溶液中确实存在氧化还原介体进行微生物与电极间传递电子。
文章以硝痠鹽溶液為陰極的電子受體,在陰極室中分彆接種活性汙泥混閤菌和純反硝化單菌株,構成生物陰極微生物燃料電池(microbial fuel cell ,簡稱MFC)A-MFC和B-MFC。實驗結果錶明:在外接電阻為100Ω情況下,A-MFC和B-M FC最大輸齣電壓分彆為119.6 mV和117.2 mV ,硝痠鹽在B-M FC陰極室的平均反硝化速率為2.19 mg/(L·d),比A-MFC中的平均反硝化速率1.86 mg/(L·d)略高;掃描電鏡觀察到A-MFC和B-M FC的陰極碳佈纖維絲錶麵形貌存在差異,A-MFC中碳佈被孔狀結構物覆蓋,而B-M FC陰極碳佈被片層狀結構物所覆蓋;同時髮現A-MFC的陰極碳佈循環伏安法CV麯線上均齣現瞭明顯的還原峰,錶明A-MFC陰極碳佈上的微生物進行瞭催化還原反應,而且陰極溶液均齣現1對明顯的氧化還原電對,說明陰極溶液中確實存在氧化還原介體進行微生物與電極間傳遞電子。
문장이초산염용액위음겁적전자수체,재음겁실중분별접충활성오니혼합균화순반초화단균주,구성생물음겁미생물연료전지(microbial fuel cell ,간칭MFC)A-MFC화B-MFC。실험결과표명:재외접전조위100Ω정황하,A-MFC화B-M FC최대수출전압분별위119.6 mV화117.2 mV ,초산염재B-M FC음겁실적평균반초화속솔위2.19 mg/(L·d),비A-MFC중적평균반초화속솔1.86 mg/(L·d)략고;소묘전경관찰도A-MFC화B-M FC적음겁탄포섬유사표면형모존재차이,A-MFC중탄포피공상결구물복개,이B-M FC음겁탄포피편층상결구물소복개;동시발현A-MFC적음겁탄포순배복안법CV곡선상균출현료명현적환원봉,표명A-MFC음겁탄포상적미생물진행료최화환원반응,이차음겁용액균출현1대명현적양화환원전대,설명음겁용액중학실존재양화환원개체진행미생물여전겁간전체전자。
With the nitrate solution as the electron acceptor ,mixed bacteria from activated sludge and pure denitrifying bacteria were inoculated in the cathode chamber ,and two kinds of biocathode micro-bial fuel cells(MFCs) named A-MFC B-MFC were built .The experimental results showed that the maximum output voltages of A-MFC and B-MFC were 119.6 mV and 117.2 mV respectively when the external resistance was 100 Ω .The average denitrification rate in B-MFC was 2.19 mg/(L · d) and the average denitrification rate in A-MFC was 1.86 mg/(L · d) .The cathode carbon cloth surface morphology of A-MFC was different from that of B-MFC according to scanning electron microscope observation ,and the carbon cloth in A-MFC was covered by macroporous structure ,however the car-bon cloth in B-MFC was covered by lamellar structure .It was also found that there were an obvious reduction peak in the cyclic voltammetry(CV) curve of A-MFC cathode carbon cloth and an oxidation-reduction pair in the cathode solution of A-MFC .The results showed that there were catalytic reduc-tion reaction in A-MFC and there was electron transferring between microorganisms and cathode elec-trode in solution .