CAJ | 학술논문

以聚四氢呋喃醚二醇（ PTMG）和甲苯二异氰酸酯（ TDI）制备预聚体，再用含氢氧化单甲基丙烯酸锌盐（ HZMMA）的混合扩链剂扩链制备了不同HZMMA含量的离子聚合物/聚氨酯弹性体（ PUE）合金。采用原子力显微镜（ AFM）、动态粘弹（ DMA）、热重分析（ TG）和X射线衍射（ XRD）研究了HZMMA含量对离子聚合物/PUE合金的形态结构和性能的影响。结果表明，适量的HZM-MA 能够形成纳米级的poly-HZMMA 粒子，改善了合金中PUE的微相分离程度；poly-HZMMA 能够提高材料的储能模量和软段的最大降解温度；HZMMA发生了自聚且硬段相有结晶。
이취사경부남미이순（ PTMG）화갑분이이청산지（ TDI）제비예취체，재용함경양화단갑기병희산자염（ HZMMA）적혼합확련제확련제비료불동HZMMA함량적리자취합물/취안지탄성체（ PUE）합금。채용원자력현미경（ AFM）、동태점탄（ DMA）、열중분석（ TG）화X사선연사（ XRD）연구료HZMMA함량대리자취합물/PUE합금적형태결구화성능적영향。결과표명，괄량적HZM-MA 능구형성납미급적poly-HZMMA 입자，개선료합금중PUE적미상분리정도；poly-HZMMA 능구제고재료적저능모량화연단적최대강해온도；HZMMA발생료자취차경단상유결정。
A series of ionic polymer/polyurethane elastomer alloys were prepared by polytetramethyleneether glycol( PTMG) ,toluene diisocyanate( TDI) and the chain extenders which were consisted of dimethylthiotoluenedia-mine( DMTDA ) , dicumyl peroxide ( DCP ) and hydroxyl zinc mono-methacrylate ( HZMMA ) by the prepolymer process. The effects of different contents of HZMMA for ionic polymer/polyurethane elastomer structure and proper-ties were studied by atomic force microscopy( AFM) ,dynamic mechanical analysis( DMA) ,thermo gravimetric anal-ysis( TGA) and X-ray diffraction( XRD) . The results indicated that nano poly-HZMMA particles were got and the degree of micro phase separation of the PUE were improved when the content of HZMMA was suitable. The nano poly-HZMMA particulars enhanced the storage modulus and improved the maximum decomposition temperature of the soft segment. The HZMMA had the self-polymeric reaction forming poly-HZMMA particles and the hard sege-ments had the microcrystalline structure.