高校化学工程学报
高校化學工程學報
고교화학공정학보
JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES
2014年
5期
951-956
,共6页
张影%马学虎%兰忠%白涛
張影%馬學虎%蘭忠%白濤
장영%마학호%란충%백도
电渗析%盐水浓缩%能耗%相对浓缩率
電滲析%鹽水濃縮%能耗%相對濃縮率
전삼석%염수농축%능모%상대농축솔
electrodialysis%brine concentration%energy cost%concentrate ratio
海水资源的综合利用和环境保护的要求极大地促进了淡化后浓盐水的处理技术的发展。电渗析是盐水浓缩广泛关注和应用的技术之一,膜性能和操作条件对电渗析过程特性有着重要的影响。实验研究了以模拟海水淡化浓水(含盐量70 g?L-1)为原料的间歇循环电渗析过程,以浓度150 g?L-1、能耗120 kWh?(tNaCl)-1,为目标,研究了浓室流量、浓淡室流量比、操作温度、操作电压对能耗和相对浓缩率的影响。实验结果表明,温度和浓室流量对实验结果影响不大,而电压和浓淡室流量比影响比较大,实验所得最佳操作条件为浓室流量250 L?h-1,浓淡室流量比2:3,电压19V和操作温度30℃。
海水資源的綜閤利用和環境保護的要求極大地促進瞭淡化後濃鹽水的處理技術的髮展。電滲析是鹽水濃縮廣汎關註和應用的技術之一,膜性能和操作條件對電滲析過程特性有著重要的影響。實驗研究瞭以模擬海水淡化濃水(含鹽量70 g?L-1)為原料的間歇循環電滲析過程,以濃度150 g?L-1、能耗120 kWh?(tNaCl)-1,為目標,研究瞭濃室流量、濃淡室流量比、操作溫度、操作電壓對能耗和相對濃縮率的影響。實驗結果錶明,溫度和濃室流量對實驗結果影響不大,而電壓和濃淡室流量比影響比較大,實驗所得最佳操作條件為濃室流量250 L?h-1,濃淡室流量比2:3,電壓19V和操作溫度30℃。
해수자원적종합이용화배경보호적요구겁대지촉진료담화후농염수적처리기술적발전。전삼석시염수농축엄범관주화응용적기술지일,막성능화조작조건대전삼석과정특성유착중요적영향。실험연구료이모의해수담화농수(함염량70 g?L-1)위원료적간헐순배전삼석과정,이농도150 g?L-1、능모120 kWh?(tNaCl)-1,위목표,연구료농실류량、농담실류량비、조작온도、조작전압대능모화상대농축솔적영향。실험결과표명,온도화농실류량대실험결과영향불대,이전압화농담실류량비영향비교대,실험소득최가조작조건위농실류량250 L?h-1,농담실류량비2:3,전압19V화조작온도30℃。
The demand of comprehensive utilization of sea water and the requirement of environment protection promote the development of technologies to concentrate salt water. The electrodialysis has been applied extensively to salt water concentration. The electrodialysis process is strongly affected by the membrane characteristics and the operating conditions. To investigate the performance of electrodialysis in concentrating salt water, the intermittent circulating electrodialysis experiments were carried out with a NaCl solution of 70 g?L-1, oriented to the target that concentration higher than 150 gNaCl?L-1? while energy cost less than 120 kWh?(tNaCl)-1. The influence of solution flow rate, flow-rate ratio, temperature, and voltage on energy cost and concentrating ratio were examined. Experimental results show that the influence of concentrated solution flow rate and temperature on energy cost and concentrate ratio is ignorable, while the influence of the voltage and the flow-rate ratio is significant. The optimal membrane performance was obtained under a condition of 250 L?h-1, 2:3, 19 V and 30℃.