CAJ | 학술논문

氯化钯在三水合四丁基氟化铵(TBAF·3H2O)中当场生成纳米钯，对碘甲苯与丙烯酸丁酯在纳米钯/四丁基氟化铵体系的催化下，选择性合成对甲基肉桂酸丁酯，反应收率高、后处理简单且催化体系可以回收重复使用，产物结构经由NMR和MS确证。
록화파재삼수합사정기불화안(TBAF·3H2O)중당장생성납미파，대전갑분여병희산정지재납미파/사정기불화안체계적최화하，선택성합성대갑기육계산정지，반응수솔고、후처리간단차최화체계가이회수중복사용，산물결구경유NMR화MS학증。
Pd nanoparticles were generated in situ from PdCl2 in tetrabutylammonium fluoride (TBAF·3H2O). Butyl 3-p-tolylacrylate was synthesized by the reaction of 1-iodo-4-methylbenzene and butyl acrylate in the presence of nano-pd/TBAF as catalyst. The reaction was readily performed with good yield under mild conditions. Moreover, the catalytic system could be recovered and reused several times in the reaction. The structure of the product was characterized with NMR and MS spectra.