当代化工
噹代化工
당대화공
CONTEMPORARY CHEMICAL INDUSTRY
2014年
10期
2078-2083
,共6页
宫希杰%谷崇%叶妮雅%李晓芳%张梁%雷良才
宮希傑%穀崇%葉妮雅%李曉芳%張樑%雷良纔
궁희걸%곡숭%협니아%리효방%장량%뢰량재
RAFT%嵌段共聚物%合成%应用
RAFT%嵌段共聚物%閤成%應用
RAFT%감단공취물%합성%응용
RAFT%Block copolymers%Synthesis%Application
RAFT聚合具有反应条件温和,对单体纯度和环境的要求相对较低等优势,近年来通过RAFT方法制备嵌段共聚物已经受到了高分子化学领域研究者的广泛关注。简要介绍了近10年来通过 RAFT 方法制备嵌段共聚物所常用的 RAFT试剂和单体的研究进展,主要介绍了近10年来线型两嵌段、三嵌段共聚物和星型嵌段共聚物的RAFT聚合及应用。
RAFT聚閤具有反應條件溫和,對單體純度和環境的要求相對較低等優勢,近年來通過RAFT方法製備嵌段共聚物已經受到瞭高分子化學領域研究者的廣汎關註。簡要介紹瞭近10年來通過 RAFT 方法製備嵌段共聚物所常用的 RAFT試劑和單體的研究進展,主要介紹瞭近10年來線型兩嵌段、三嵌段共聚物和星型嵌段共聚物的RAFT聚閤及應用。
RAFT취합구유반응조건온화,대단체순도화배경적요구상대교저등우세,근년래통과RAFT방법제비감단공취물이경수도료고분자화학영역연구자적엄범관주。간요개소료근10년래통과 RAFT 방법제비감단공취물소상용적 RAFT시제화단체적연구진전,주요개소료근10년래선형량감단、삼감단공취물화성형감단공취물적RAFT취합급응용。
RAFT polymerization hasmanyadvantages, such asmild reaction conditions, relatively low requirements forpurity of the monomer,andso on. In recent years, preparation of block copolymers by RAFT has been paid widespread attention in the field of polymer chemistry. Inthis article, RAFT agents and monomers were introduced. The recent research progress in preparation of block copolymers by RAFT was discussed, and RAFT polymerization and application of linear diblock, triblock and star copolymerswere introduced.