CAJ | 학술논문

选取一个100 MW燃煤电厂对氯化铜改性氧化铝和氯化铜改性沸石进行喷射脱汞实验，应用EPA 30B标准方法对静电除尘器（ESP）前后烟气中的汞价态分布进行了采样和测试。研究了吸附剂喷射量对烟气中汞脱除率的影响。现场测试的汞平衡结果为77.1%～111.5%。经修正的汞平衡结果表明，吸附剂喷射量越大，脱汞率越高。改性氧化铝的脱汞率最高可达30.6%，改性沸石的脱汞率最高可达29.2%。喷射非碳基吸附剂后烟气中元素汞（Hg0）显著下降，在喷射量为0.22 g·m-3时，两种吸附剂可将烟气中Hg0比例由40%降低至22%左右，减少的Hg0主要转化为HgP。非碳基吸附剂与湿法脱硫（WFGD）系统协同使用可以有效减少Hg0向大气中的排放。
선취일개100 MW연매전엄대록화동개성양화려화록화동개성비석진행분사탈홍실험，응용EPA 30B표준방법대정전제진기（ESP）전후연기중적홍개태분포진행료채양화측시。연구료흡부제분사량대연기중홍탈제솔적영향。현장측시적홍평형결과위77.1%～111.5%。경수정적홍평형결과표명，흡부제분사량월대，탈홍솔월고。개성양화려적탈홍솔최고가체30.6%，개성비석적탈홍솔최고가체29.2%。분사비탄기흡부제후연기중원소홍（Hg0）현저하강，재분사량위0.22 g·m-3시，량충흡부제가장연기중Hg0비례유40%강저지22%좌우，감소적Hg0주요전화위HgP。비탄기흡부제여습법탈류（WFGD）계통협동사용가이유효감소Hg0향대기중적배방。
The mercury removal from the flue gas discharged from a 100 MW coal-fired power plant in China by non-carbon sorbents CuCl2 impregnated alumina and zeolite were experimentally investigated in this paper. When the sorbent were added into, the mercury speciation in flue gas across ESP was directly sampled and analyzed using EPA 30B standard method. The effect of injection rate was studied. The mercury balances measured on-site were between 77.1%-111.5%, and the results of mercury balance after correction suggested that the rates of mercury removal increased with increase of injecting amounts, and was up to 30.6% for modified alumina and 29.2% for modified zeolite. The Hg0 content in flue gas reduced considerably after sorbent injection, and decreased from 40% to 22% when the sorbent injection rate was 0.22 g·m-3. Non-carbon sorbent injection combined with WFGD system could be an effective technology for controlling mercury emission of coal-fired power plant.