化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
11期
4321-4324
,共4页
章学来%孟祥来%赵群志%李春蕾
章學來%孟祥來%趙群誌%李春蕾
장학래%맹상래%조군지%리춘뢰
冰蓄冷%过冷度%成核%纳米材料%相变
冰蓄冷%過冷度%成覈%納米材料%相變
빙축랭%과랭도%성핵%납미재료%상변
ice thermal storage%supercooling degree%nucleation%nanomaterials%phase change
在对内融冰式蓄冰槽内不同水层的水进行过冷度测试中发现上层水的过冷度较大。为了降低水的过冷度和冷水机组能耗,通过实验的方法对不同的成核添加剂进行筛选测试,结果显示纳米氧化铜不但在降低过冷度方面效果显著,而且提高了蓄冰效率。最后获取了一定质量分散剂下最佳纳米氧化铜的质量分数,即在-5℃的制冰温度下,质量分数为0.10%的氧化铜悬浊液为最佳配比。在实验过程中发现水的过冷度还与换热介质的传热温差有关,温差越大过冷度越小。
在對內融冰式蓄冰槽內不同水層的水進行過冷度測試中髮現上層水的過冷度較大。為瞭降低水的過冷度和冷水機組能耗,通過實驗的方法對不同的成覈添加劑進行篩選測試,結果顯示納米氧化銅不但在降低過冷度方麵效果顯著,而且提高瞭蓄冰效率。最後穫取瞭一定質量分散劑下最佳納米氧化銅的質量分數,即在-5℃的製冰溫度下,質量分數為0.10%的氧化銅懸濁液為最佳配比。在實驗過程中髮現水的過冷度還與換熱介質的傳熱溫差有關,溫差越大過冷度越小。
재대내융빙식축빙조내불동수층적수진행과랭도측시중발현상층수적과랭도교대。위료강저수적과랭도화랭수궤조능모,통과실험적방법대불동적성핵첨가제진행사선측시,결과현시납미양화동불단재강저과랭도방면효과현저,이차제고료축빙효솔。최후획취료일정질량분산제하최가납미양화동적질량분수,즉재-5℃적제빙온도하,질량분수위0.10%적양화동현탁액위최가배비。재실험과정중발현수적과랭도환여환열개질적전열온차유관,온차월대과랭도월소。
Experiment on different depth of water tank supercooling degree was carried out. The results show that the supercooling degree of the upper water in ice storage tank is higher. In order to reduce the supercooling degree of the water and energy consumption of the chiller, different nucleation additives are tested and it is found that adding nano-copper oxide can reduce the supercooling degree and improve the ice storage efficiency. Appropriate mass fraction of copper oxide nanoparticles is obtained under a certain quality dispersant. When the ice-making temperature is-5℃,0.10% mass fraction copper oxide suspension is at the top. Supercooling degree of water is also associated with the temperature difference of heat transfer medium. The higher the difference in temperature is, the smaller the supercooling degree.