化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
11期
4315-4320
,共6页
纳米微粒%分散剂%溴化锂溶液%表面张力%沸腾温度
納米微粒%分散劑%溴化鋰溶液%錶麵張力%沸騰溫度
납미미립%분산제%추화리용액%표면장력%비등온도
nano-particles%dispersant%LiBr aqueous solution%surface tension%boiling temperature
在纯溴化锂溶液中加入纳米微粒或分散剂,对比测试其与纯溴化锂溶液的表面张力和沸腾温度的数据,并从所用分散剂的分子结构和纳米微粒的尺寸及外部轮廓的角度出发,定性推测不同种类分散剂及纳米微粒对溴化锂溶液表面张力和沸腾温度的影响。试验发现,添加分散剂溶液的表面张力明显降低,其沸腾温度也相应减小;固体纳米微粒因其填充加热表面凹坑使溶液的沸腾温度有所升高。对于加入纳米微粒及其分散剂的溴化锂溶液,溶液表面张力衰减的正效应因素和纳米微粒填充凹坑的负效应因素的耦合影响将对其沸腾温度产生重要影响。
在純溴化鋰溶液中加入納米微粒或分散劑,對比測試其與純溴化鋰溶液的錶麵張力和沸騰溫度的數據,併從所用分散劑的分子結構和納米微粒的呎吋及外部輪廓的角度齣髮,定性推測不同種類分散劑及納米微粒對溴化鋰溶液錶麵張力和沸騰溫度的影響。試驗髮現,添加分散劑溶液的錶麵張力明顯降低,其沸騰溫度也相應減小;固體納米微粒因其填充加熱錶麵凹坑使溶液的沸騰溫度有所升高。對于加入納米微粒及其分散劑的溴化鋰溶液,溶液錶麵張力衰減的正效應因素和納米微粒填充凹坑的負效應因素的耦閤影響將對其沸騰溫度產生重要影響。
재순추화리용액중가입납미미립혹분산제,대비측시기여순추화리용액적표면장력화비등온도적수거,병종소용분산제적분자결구화납미미립적척촌급외부륜곽적각도출발,정성추측불동충류분산제급납미미립대추화리용액표면장력화비등온도적영향。시험발현,첨가분산제용액적표면장력명현강저,기비등온도야상응감소;고체납미미립인기전충가열표면요갱사용액적비등온도유소승고。대우가입납미미립급기분산제적추화리용액,용액표면장력쇠감적정효응인소화납미미립전충요갱적부효응인소적우합영향장대기비등온도산생중요영향。
Surface tension and boiling temperature were determined with a contrastive experimental method for LiBr aqueous solutions without and with nano-particles or dispersants added in a same quantity of recipe. The influence of different dispersants and nano-particles on properties of LiBr aqueous solution was conjectured and analyzed qualitatively through the molecular structure of dispersant and the external contour and size of nano-particles. It is found experimentally that the surface tension of solution reduces significantly with dispersants added and its boiling temperature decreases correspondingly. The boiling temperature is increased with nano-particles added because the particles will fill the micro-pits on the heating surface. The boiling temperature of LiBr aqueous solution added with nano-particles and its relevant dispersants have a great influence on the positive effect of lower surface tension and negative effect that nano-particles fill the pits.