化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
11期
3013-3020,3074
,共9页
朱彩艳%马慧敏%张强%张田林
硃綵豔%馬慧敏%張彊%張田林
주채염%마혜민%장강%장전림
功能单体%聚合物%吸附%脱附
功能單體%聚閤物%吸附%脫附
공능단체%취합물%흡부%탈부
functional monomer%polymers%adsorption%desorption
阐述了不饱和羧酸类(甲基丙烯酸、丙烯酸和乙烯基苯甲酸)、芳香杂环类(吡啶类、咪唑类和喹啉类)、水杨醛类希夫碱以及Salen配体等功能单体的性能、优点、用途等方面的研究进展,以及基于上述单体制备的离子印迹聚合物吸附特性和应用性能等,展望了离子印迹聚合物功能单体未来的发展方向:一是功能单体种类需要进一步丰富;二是其所具有的性能和功能等还有待于完善。其中,季铵盐化5-氯甲基水杨醛类希夫碱功能单体具有强亲水性能和多官能团特性,对其进行性能研究将会是探索此类功能单体在应用方面的热点内容之一。
闡述瞭不飽和羧痠類(甲基丙烯痠、丙烯痠和乙烯基苯甲痠)、芳香雜環類(吡啶類、咪唑類和喹啉類)、水楊醛類希伕堿以及Salen配體等功能單體的性能、優點、用途等方麵的研究進展,以及基于上述單體製備的離子印跡聚閤物吸附特性和應用性能等,展望瞭離子印跡聚閤物功能單體未來的髮展方嚮:一是功能單體種類需要進一步豐富;二是其所具有的性能和功能等還有待于完善。其中,季銨鹽化5-氯甲基水楊醛類希伕堿功能單體具有彊親水性能和多官能糰特性,對其進行性能研究將會是探索此類功能單體在應用方麵的熱點內容之一。
천술료불포화최산류(갑기병희산、병희산화을희기분갑산)、방향잡배류(필정류、미서류화규람류)、수양철류희부감이급Salen배체등공능단체적성능、우점、용도등방면적연구진전,이급기우상술단체제비적리자인적취합물흡부특성화응용성능등,전망료리자인적취합물공능단체미래적발전방향:일시공능단체충류수요진일보봉부;이시기소구유적성능화공능등환유대우완선。기중,계안염화5-록갑기수양철류희부감공능단체구유강친수성능화다관능단특성,대기진행성능연구장회시탐색차류공능단체재응용방면적열점내용지일。
This paper is aimed to describe the research progress in several functional monomers in terms of their performance,advantages,and applications. The elaborated functional monomer contains the categories of organic acids (methacrylic acid,acrylic acid and vinyl benzoic acid),aromatic heterocyclic (pyridine , imidazole , amides and quinolines) , the Schiff base and Salen ligand. Furthermore,the adsorption characteristics and application performances of ion-imprinted polymer produced with the above-described monomers are illustrated. Combined with our recent works in salicylaldehyde Schiff bases functional monomer containing quaternary ammonium ion , the development trend of functional monomer is also prospected. Not only species of functional monomers requires further enriched,but also their function and performance have to be improved. Among those, the functional monomer of 5-chloro methyl salicylic aldehyde Schiff’s base modified with quaternary ammonium salt possesses shows strong hydrophilic properties and multi-functional characteristics,and a future research focus shall be the investigation on its performances in the application of functional monomers.