有色金属科学与工程
有色金屬科學與工程
유색금속과학여공정
JIANGXI NONFERROUS METALS
2014年
5期
79-81,122
,共4页
王旭%周才英%廖春发
王旭%週纔英%廖春髮
왕욱%주재영%료춘발
熔盐电解%钨铜合金%温场%电极电位
鎔鹽電解%鎢銅閤金%溫場%電極電位
용염전해%오동합금%온장%전겁전위
molten salt electrolysis%tungsten-copper alloy%temperature field%electrode potential
在熔盐电解法由Na2WO4和CuO制取钨铜合金粉体的研究基础上,分析电解槽内的温度场分布,特别是电极区域的温度分布情况对电解行为的影响。通过位移法测量,采取比较法分析实验误差,结果表明:电解过程中2个主要的外部条件,即电解槽内温场分布与电场分布是联动的;温度条件影响着电极电位;同时,外部槽电压通过电流扰动槽内温场,使电极区域温场分布不均。
在鎔鹽電解法由Na2WO4和CuO製取鎢銅閤金粉體的研究基礎上,分析電解槽內的溫度場分佈,特彆是電極區域的溫度分佈情況對電解行為的影響。通過位移法測量,採取比較法分析實驗誤差,結果錶明:電解過程中2箇主要的外部條件,即電解槽內溫場分佈與電場分佈是聯動的;溫度條件影響著電極電位;同時,外部槽電壓通過電流擾動槽內溫場,使電極區域溫場分佈不均。
재용염전해법유Na2WO4화CuO제취오동합금분체적연구기출상,분석전해조내적온도장분포,특별시전겁구역적온도분포정황대전해행위적영향。통과위이법측량,채취비교법분석실험오차,결과표명:전해과정중2개주요적외부조건,즉전해조내온장분포여전장분포시련동적;온도조건영향착전겁전위;동시,외부조전압통과전류우동조내온장,사전겁구역온장분포불균。
Based on the research of preparing tungsten copper alloy powder from Na 2WO4 and CuO by molten salt electrolysis method, the temperature field distribution of the electrolysis cell and the influence of the electrochemical behavior around temperature distribution nearby the electrode area are analyzed. Temperature is measured by the displacement method and the experimental error is analyzed. The results show that temperature field distribution and electric field distribution in the electrolytic cell interact with each other, and the electrode potential is affected by temperature conditions. In the meanwhile, the external electric field disturbs the temperature field in electrolysis cell to make the uneven distribution of temperature field around electrode area.